Synthesis of High Molecular Weight Poly(p-benzamide)s

被引：14
|
作者：
Badoux, Michael [1 ]
Kilbinger, Andreas F. M. [1 ]
机构：
[1] Univ Fribourg, Chem Dept, Chemin Musee 9, CH-1700 Fribourg, Switzerland
来源：
MACROMOLECULES | 2017年 / 50卷 / 11期
基金：
瑞士国家科学基金会;
关键词：
CHAIN-GROWTH POLYCONDENSATION; N-PHOSPHONIUM SALTS; AROMATIC POLYAMIDES; TRIPHENYLPHOSPHINE; PYRIDINES; HEXACHLOROETHANE; ARCHITECTURE; REDUCTIONS; PHOSPHITES; ARAMIDE;
D O I：
10.1021/acs.macromol.7b00515
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymerization of aromatic para-amino acid ester derivatives was studied using model compounds. Mechanistic and kinetic experiments led to the discovery of some side reactions. Finally, high molecular weight poly(p-benzamide)s were synthesized and characterized. The use of highly reactive pentafluorophenol ester lead to polymers up to molecular weights of around SO 000 Da. Poly(benzamides) carrying both N-alkyl or N-benzyl groups on the amine could be polymerized to high molecular weight.
引用
收藏
页码：4188 / 4197
页数：10
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