Synthesis of High Molecular Weight Poly(p-benzamide)s

被引：14

作者：

Badoux, Michael ^{[1
]}

Kilbinger, Andreas F. M. ^{[1
]}

机构：

[1] Univ Fribourg, Chem Dept, Chemin Musee 9, CH-1700 Fribourg, Switzerland

来源：

MACROMOLECULES | 2017年 / 50卷 / 11期

基金：

瑞士国家科学基金会;

关键词：

CHAIN-GROWTH POLYCONDENSATION; N-PHOSPHONIUM SALTS; AROMATIC POLYAMIDES; TRIPHENYLPHOSPHINE; PYRIDINES; HEXACHLOROETHANE; ARCHITECTURE; REDUCTIONS; PHOSPHITES; ARAMIDE;

D O I：

10.1021/acs.macromol.7b00515

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymerization of aromatic para-amino acid ester derivatives was studied using model compounds. Mechanistic and kinetic experiments led to the discovery of some side reactions. Finally, high molecular weight poly(p-benzamide)s were synthesized and characterized. The use of highly reactive pentafluorophenol ester lead to polymers up to molecular weights of around SO 000 Da. Poly(benzamides) carrying both N-alkyl or N-benzyl groups on the amine could be polymerized to high molecular weight.

引用

页码：4188 / 4197

页数：10

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