Metal-Organic Framework-Derived Guerbet Catalyst Effectively Differentiates between Ethanol and Butanol

被引：37
|
作者：
Neumann, Constanze N. [1 ]
Rozeveld, Steven J. [2 ]
Yu, Mingzhe [2 ]
Rieth, Adam J. [1 ]
Dinca, Mircea [1 ]
机构：
[1] MIT, Dept Chem, 77 Massachusetts Ave, Cambridge, MA 02139 USA
[2] Dow Chem Co USA, Core R&D, Midland, MI 48674 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 44期
基金：
美国国家科学基金会;
关键词：
N-BUTANOL; UPGRADING ETHANOL; 1-BUTANOL; CONVERSION; BIOFUEL; ACID;
D O I：
10.1021/jacs.9b08968
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
RuNi nanoparticles supported on a metal-organic framework (RuNi@MOF) and formed in situ from a ruthenium complex enclosed inside a nickel-based MOF act as a highly active catalyst for the Guerbet reaction of ethanol to I-butanol, providing turnover numbers up to 725 000 Ru-1. Negligible activity of the RuNi@MOF ethanol upgrading catalyst system toward chemically similar 1-butanol makes it possible to synthesize the competent Guerbet substrate 1-butanol with >99% selectivity.
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页码：17477 / 17481
页数：5
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