Metal-Organic Framework-Derived Guerbet Catalyst Effectively Differentiates between Ethanol and Butanol

被引：37

作者：

Neumann, Constanze N. ^{[1
]}

Rozeveld, Steven J. ^{[2
]}

Yu, Mingzhe ^{[2
]}

Rieth, Adam J. ^{[1
]}

Dinca, Mircea ^{[1
]}

机构：

[1] MIT, Dept Chem, 77 Massachusetts Ave, Cambridge, MA 02139 USA

[2] Dow Chem Co USA, Core R&D, Midland, MI 48674 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 44期

基金：

美国国家科学基金会;

关键词：

N-BUTANOL; UPGRADING ETHANOL; 1-BUTANOL; CONVERSION; BIOFUEL; ACID;

D O I：

10.1021/jacs.9b08968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

RuNi nanoparticles supported on a metal-organic framework (RuNi@MOF) and formed in situ from a ruthenium complex enclosed inside a nickel-based MOF act as a highly active catalyst for the Guerbet reaction of ethanol to I-butanol, providing turnover numbers up to 725 000 Ru-1. Negligible activity of the RuNi@MOF ethanol upgrading catalyst system toward chemically similar 1-butanol makes it possible to synthesize the competent Guerbet substrate 1-butanol with >99% selectivity.

引用

页码：17477 / 17481

页数：5

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