A new ligand, 10-ethylphenothiazinyl - 3 - yl - methylene thiosemicarbazon (HL) and its complexes ML2 (M=Zn2+, Cd2+), which exhibit intensive two-photon excited (TPE) fluorescence at 800 nm laser pulses in femtosecond regime, were synthesized and characterized. The measured power dependence of the fluorescence signals provided direct evidence for TPE. All of them exhibited a large two-photon absorptive cross section and, more importantly from the application point of view, high photochemical/photothermal stability.
机构:Harbin University of Science and Technology,Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province; College of Chemical and Environmental Engineering
ZhaoDi Yang
GuiLing Zhang
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机构:Harbin University of Science and Technology,Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province; College of Chemical and Environmental Engineering
GuiLing Zhang
JiKang Feng
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机构:Harbin University of Science and Technology,Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province; College of Chemical and Environmental Engineering
JiKang Feng
AiMin Ren
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机构:Harbin University of Science and Technology,Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province; College of Chemical and Environmental Engineering