Seasoning hydrous pyrolysis reactor vessels

被引：1

作者：

Snowdon, Lloyd R. ^{[1
,2
]}

Jiang, Chunqing ^{[2
]}

Nightingale, Michael ^{[1
]}

Snowdon, Ryan W. ^{[1
]}

机构：

[1] Univ Calgary, Dept Geosci, 2500 Univ Dr NW, Calgary, AB T2N 1N4, Canada

[2] Geol Survey Canada, 3303 33 St NW, Calgary, AB T2L 2A7, Canada

来源：

ORGANIC GEOCHEMISTRY | 2017年 / 110卷

关键词：

Stainless steel reactor; Hydrous pyrolysis; Seasoning; Hydrogen generation; STAINLESS-STEEL; KEROGEN; WATER;

D O I：

10.1016/j.orggeochem.2017.04.011

中图分类号：

P3 [地球物理学]; P59 [地球化学];

学科分类号：

0708 ; 070902 ;

摘要：

Fresh stainless steel (316) surfaces were blackened by heating at 250 degrees C for 2-20 h in the presence of water and argon. Headspace gas after heating contained up to 1 mol% molecular hydrogen. These results indicate that the water oxidized the metal surfaces causing the blackening and released molecular hydrogen. Oxidation must be considered as an alternative or complementary process to carburization during the seasoning of 316 stainless steel reactor vessels during hydrous pyrolysis. Crown Copyright (C) 2017 Published by Elsevier Ltd. All rights reserved.

引用

页码：57 / 59

页数：3

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