Recent Development of Light-Mediated Carboxylation Using CO2 as the Feedstock

被引：67
|
作者：
Hou, Jing [1 ]
Li, Jie-Sheng [1 ]
Wu, Jie [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 08期
基金：
中国国家自然科学基金;
关键词：
carbocarboxylation; carbon dioxide; hydrocarboxylation; photoredox; transition metals; C-H BONDS; CATALYZED DIRECT CARBOXYLATION; CARBON-DIOXIDE; VISIBLE-LIGHT; REGIOSELECTIVE HYDROCARBOXYLATION; PHOTOCATALYTIC FIXATION; PHOTOREDOX CATALYSIS; DRIVEN CARBOXYLATION; NICKEL CATALYSIS; CONTINUOUS-FLOW;
D O I：
10.1002/ajoc.201800226
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
CO2 is an attractive renewable C1 feedstock owing to its abundance, low cost, and nontoxicity. Developing new catalytic protocols for CO2 utilization is of great importance. With the development of photoredox catalysis over the past decades, light-driven CO2 fixation has attracted significant attention. This Review will focus on recent development of light-promoted carboxylation utilizing CO2 as a C1 source to synthesize value-added chemicals in the area of organic synthesis.
引用
收藏
页码：1439 / 1447
页数：9
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