Recent Advances in Light-Induced Carboxylation of Organic (Pseudo)Halides with CO2

被引：5
|
作者：
Fan, Zhengning [1 ]
Yi, Yaping [1 ]
Xi, Chanjuan [1 ,2 ]
机构：
[1] Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 08期
基金：
中国国家自然科学基金;
关键词：
carbon dioxide; carboxylation; photocatalysis; (pseudo)halides; carboxylic acids; PALLADIUM-CATALYZED CARBOXYLATION; C-H BONDS; CARBON-DIOXIDE; ALLYLIC ALCOHOLS; STYRENES; BROMIDES; HYDROCARBOXYLATION; TRANSFORMATIONS; OPPORTUNITIES; ACTIVATION;
D O I：
10.1002/ajoc.202200207
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Carbon dioxide is an ideal C1 source in organic synthesis as a precursor for the carboxyl group. With the development of photocatalysis, the carboxylation reactions with CO2 incorporation could be carried out in a more environmental and sustainable manner without the addition of stoichiometric metallic reductants. This minireview summarizes the recent development in light-induced carboxylation of organic (pseudo)halides and analogues with CO2 via C-X (X=Br, Cl, O, N, etc.) bond cleavage.
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页数：10
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