TiO2/TiO2-x N y nanocomposite and its acetaldehyde photodecomposition ability

被引:9
|
作者
Liu, Bin [1 ,2 ]
Wang, Yuhua [1 ]
Yin, Shu [2 ]
Sato, Tsugio [2 ]
机构
[1] Lanzhou Univ, Dept Mat Sci, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
[2] Tohoku Univ, IMRAM, Sendai, Miyagi 980, Japan
关键词
Visible-light induced; Photocatalyst; Singlet oxygen; Acetaldehyde degradations; NITROGEN-DOPED TITANIA; PHOTOCATALYTIC OXIDATION; TIO2; FORMALDEHYDE; IRRADIATION; DEGRADATION; PARTICLES; ANATASE; FILM;
D O I
10.1007/s11164-010-0112-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitrogen-doped titania was coupled with the commercial titania nanoparticles by mechanical milling in liquid medium. The as-prepared nanocomposites (TiO2/TiO2-x N (y) ) were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area, UV-Vis spectroscopy, chemiluminescence, and acetaldehyde decomposition activity techniques. When a small amount of nitrogen-doped titania was added into the commercial titania, higher intensity and longer lifetime of O-1(2) was observed, and the photocatalytic activity was efficiently improved. The TiO2-x N (y) acts as the acceptor of photoinduced holes. The recombination of the electron-hole was effectively depressed by the heterogeneous electron transfer. This could be an effective way to obtain highly active photocatalysts.
引用
收藏
页码:39 / 49
页数:11
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