Transition-Metal-Catalyzed Three-Component Difunctionalizations of Alkenes

被引：215
|
作者：
Zhang, Ji-Shu [1 ]
Liu, Long [2 ]
Chen, Tieqiao [1 ,2 ]
Han, Li-Biao [3 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Hainan Univ, Key Lab, Minist Educ Adv Mat Trop Isl Resources, Coll Mat & Chem Engn, Haikou 570228, Hainan, Peoples R China
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2018年 / 13卷 / 17期
关键词：
alkenes; difunctionalization; functionalized alkanes; multicomponent reactions; step-economic efficiency; CROSS-COUPLING REACTIONS; ARYL GRIGNARD-REAGENTS; UNACTIVATED ALKENES; CARBONYL-COMPOUNDS; TERMINAL ALKENES; ALKYL-HALIDES; INTERMOLECULAR CYANOTRIFLUOROMETHYLATION; ENANTIOSELECTIVE 1,2-DIFUNCTIONALIZATION; IODINE(III)-MEDIATED HALOGENATIONS; SODIUM TRIFLUOROMETHANESULFINATE;
D O I：
10.1002/asia.201800647
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three-component reactions can directly convert three reactants into the desired products in one pot and thus greatly shorten the synthetic path. Recently, transition-metal catalysis has been applied in the difunctionalization of alkenes and remarkable progress has been achieved to facilitate the construction of a wide range of functional molecules with high atom- and step-economic efficiency. This Focus Review highlights recent advances in this field.
引用
收藏
页码：2277 / 2291
页数：15
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