High sulfur loading application with the assistance of an extremely light-weight multifunctional layer on the separator for lithium-sulfur batteries

被引:4
|
作者
Qiu, Xiang-yun [1 ,2 ]
Hua, Qing-song [1 ,2 ]
Dai, Zuo-qiang [1 ,2 ]
Zheng, Zong-min [1 ,2 ]
Wang, Fa-jie [1 ,2 ]
Zhang, Hong-xin [1 ,2 ]
机构
[1] Qingdao Univ, Sch Mech & Elect Engn, Power & Energy Storage Syst Res Ctr, 308 Ningxia Rd, Qingdao 266071, Shandong, Peoples R China
[2] Natl Engn Res Ctr Intelligent Elect Vehicle Power, 308 Ningxia Rd, Qingdao 266071, Shandong, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Lithium-sulfur batteries; Multifunction separator; Reduced graphene oxide; High sulfur loading; HIGH-ENERGY DENSITY; LI-S BATTERIES; CARBON; PERFORMANCE; CATHODE; MECHANISM; DESIGN;
D O I
10.1007/s11581-019-03271-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For high-energy density lithium-sulfur (Li-S) batteries, the effective active material loading, cyclic stability, and modification hardly any effect on energy density are crucial factors, but these three indicators seem contradictory in most case. In this paper, cells with a high sulfur loading, 4.3 mg cm(-2), demonstrate excellent performances with the assistance of reduced graphene oxide (rGO) modified on the separator, and the density of modified layer is only 0.1 mg cm(-2), which is hardly any effect on energy density. Moreover, in order to understand the improvement mechanism of the modified layer, graphene oxide (GO) modified layer is also to be applied for comparison, which is also helpful to establish cognition to select other modification layers. Most important of all, the application of high sulfur loading is generally required for practical Li-S batteries and the extremely light-weight modified layer is beneficial to the exertion of the whole energy density.
引用
收藏
页码:1139 / 1147
页数:9
相关论文
共 50 条
  • [31] Surface design for high ion flux separator in lithium-sulfur batteries
    Li, Rong
    Li, Jiaqi
    Wang, Xin
    Jian, Caifeng
    Wu, Xinxiang
    Zhong, Benhe
    Chen, Yanxiao
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2024, 654 : 13 - 24
  • [32] A trilayer separator with dual function for high performance lithium-sulfur batteries
    Song, Rensheng
    Fang, Ruopian
    Wen, Lei
    Shi, Ying
    Wang, Shaogang
    Li, Feng
    JOURNAL OF POWER SOURCES, 2016, 301 : 179 - 186
  • [33] Multifunctional Asymmetric Separator Constructed by Polyacrylonitrile-Derived Nanofibers for Lithium-Sulfur Batteries
    Gu, Ming
    Wang, Jiayu
    Song, Zihao
    Li, Chengming
    Wang, Weikun
    Wang, Anbang
    Huang, Yaqin
    ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (44) : 51241 - 51251
  • [34] Advanced Separator Enabled by Sulfur Defect Engineering for High-Performance Lithium-Sulfur Batteries
    Gao, Yangchen
    Bai, Yu
    Sun, Rui
    Qu, Meixiu
    Wang, Mengyuan
    Peng, Lin
    Wang, Zhenhua
    Sun, Wang
    Sun, Kening
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (20) : 6957 - 6966
  • [35] Systematic Exploration of the Role of a Modified Layer on the Separator in the Electrochemistry of Lithium-Sulfur Batteries
    Tian, Wenzhi
    Xi, Baojuan
    Mao, Hongzhi
    Zhang, Junhao
    Feng, Jinkui
    Xiong, Shenglin
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (36) : 30306 - 30313
  • [36] Research Progress of Separator Materials for Lithium-Sulfur Batteries
    Kang, Wei-min
    Ma, Xiao-min
    Zhao, Yi-xia
    Zhao, Hui-hui
    Cheng, Bo-wen
    Liu, Yan-bo
    ACTA POLYMERICA SINICA, 2015, (11): : 1258 - 1265
  • [37] The surface modification of the separator for electrocatalyst in lithium-sulfur batteries
    Yu Yu
    Zejing Lin
    Wenlong Huang
    Huitian Liu
    Yuansheng Liu
    Zhongqiang Shan
    Ionics, 2020, 26 : 1129 - 1138
  • [38] The surface modification of the separator for electrocatalyst in lithium-sulfur batteries
    Yu, Yu
    Lin, Zejing
    Huang, Wenlong
    Liu, Huitian
    Liu, Yuansheng
    Shan, Zhongqiang
    IONICS, 2020, 26 (03) : 1129 - 1138
  • [39] Insight into the loading temperature of sulfur on sulfur/carbon cathode in lithium-sulfur batteries
    Ye, Huan
    Yin, Ya-Xia
    Guo, Yu-Guo
    ELECTROCHIMICA ACTA, 2015, 185 : 62 - 68
  • [40] Strategies toward High-Loading Lithium-Sulfur Batteries
    Wang, Tao
    He, Jiarui
    Cheng, Xin-Bing
    Zhu, Jian
    Lu, Bingan
    Wu, Yuping
    ACS ENERGY LETTERS, 2023, 8 (01) : 116 - 150