RhCl(CO)(PPh3)2 catalyzed α-alkylation of ketones with alcohols

被引：32

作者：

Wang, Rui ^{[1
]}

Huang, Lina ^{[1
]}

Du, Zhengyin ^{[1
]}

Feng, Hua ^{[1
]}

机构：

[1] Northwest Normal Univ, Key Lab Ecoenvironm Related Polymer Mat, Minist Educ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 846卷

基金：

中国国家自然科学基金;

关键词：

Alkylation; Ketones; Alcohols; Hydrogen transfer; Cross coupling; LIGAND; NANOPALLADIUM; ACTIVATION; PRODUCTS; COMPLEX; ROUTE; PHASE;

D O I：

10.1016/j.jorganchem.2017.05.055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple and efficient method for alpha-alkylation of ketones with primary alcohols catalyzed by RhCl(CO)(PPh3)(2) without additional additives under mild conditions is developed. It has a wide substrate scope, high atom-efficiency and chemoselectivity. It is an environmentally friendly method to build C-C bond because water is the only byproduct. (C) 2017 Published by Elsevier B.V.

引用

页码：40 / 43

页数：4

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