Variations of the charge and open-circuit potential during the ion adsorption with the formation of irreversibly adsorbed atoms

被引：2

作者：

Podlovchenko, BI ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Moscow 119899, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2000年 / 36卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1007/BF02757699

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The transients of the current and open-circuit potential (OCP) for the Bz+/- +/- ze --> B-ad process, where B-ad is an irreversibly adsorbed atom, are described analytically. The analysis is based on the earlier obtained relationships for variations in the total charge and OCP of a hydrogen electrode during the irreversible adsorption of neutral species. A graphic method of estimating the OCP shifts and integral current transients (E-ads = const) corresponding to various surface coverages with B-ad is proposed.

引用

页码：1236 / 1240

页数：5

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