The Solid Solutions of (Cu1-YMY)2(OH)PO4 (M-Zn, Co, Ni)

被引：2
|
作者：
Viter, Vladimir N. [1 ]
机构：
[1] Kyiv Natl Univ, UA-01033 Kiev, Ukraine
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 03期
关键词：
Hydroxide phosphate; isomorphic substitution; libethenite; solid solution; synthesis; COPPER HYDROXYPHOSPHATE CU-2(OH)PO4; CATALYTIC EPOXIDATION; STYRENE;
D O I：
10.1080/10426500902893183
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solid solutions of (Cu1-YZnY)2(OH)PO4 (0 Y 0.26), (Cu1-YCoY)2(OH)PO4 (0 Y 0.10), and (Cu1-YNiY)2(OH)PO4 (0 Y 0.08) were prepared. Phosphoric acid and mixtures of hydroxide carbonates were used as starting materials. The solid solutions crystallize in the orthorhombic system, space group Pnnm. The unit cell parameters of solid solution are close to those of Cu2(OH)PO4. The IR spectra of synthesized hydroxide phosphates are similar, indicating that they have the same structure. The significant Mg, Mn substitution for Cu was not observed. The thermal decomposition of (Cu1-YCoY)2(OH)PO4 was studied.
引用
收藏
页码：602 / 608
页数：7
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