Mixed dithiolato alkylene dithiophosphate derivatives of arsenic(III) and antimony(III)

被引：13

作者：

Chauhan, HPS ^{[1
]}

Porwal, B ^{[1
]}

Singh, RK ^{[1
]}

机构：

[1] Devi Ahilya Univ, Inst Chem Sci, Indore 452001, Madhya Pradesh, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2000年 / 160卷

关键词：

dithiophosphate; arsenic; antimony;

D O I：

10.1080/10426500008043674

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed dithiolato alkylene dithiophosphate derivatives of arsenic(III) and antimony(III) with the general formula [GRAPHICS] (where, G = -CH2C(CH3)(2)CH2-; -CH2C(C2H5)(2)CH2-) have been synthesized for the first time by the replacement reactions of ethane-1,2-dithiolatoarsenic(III) chloride, ethane-1,2-dithiolatoantimony(III) chloride, toluene-3,4-dithiolatoantimony(III) chloride, respectively with sodium alkylenedithiophosphates in equimolar ratios in benzene. These new compounds are soluble in common organic solvents like benzene, chloroform and carbon tetrachloride. These have been characterised by elemental analysis, melting points as well as spectroscopic (IR and H-1. C-13 and P-31 NMR) studies and probable structures have been proposed.

引用

页码：93 / 103

页数：11

共 50 条

[21] Thiolates of arsenic(III), antimony(III), and bismuth(III) with dl-α-dihydrolipoic acid
Panayiotis V. Ioannou
Gerasimos M. Tsivgoulis
Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 897 - 909
[22] Determination of trace arsenic(III), arsenic(V), antimony(III), antimony(V) in drain by ICP equipped with hydridegeneration system
Ono, H
SECOND INTERNATIONAL CONFERENCE ON PROCESSING MATERIALS FOR PROPERTIES, 2000, : 379 - 384
[23] MANGANESE(III) OXIDATION OF ARSENIC(III) ANTIMONY(III) IN AQUEOUS SULFURIC-ACID
KAMPLI, SR
NANDIBEWOOR, ST
SAMBRANI, MI
RAJU, JR
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1989, 28 (10): : 877 - 880
[24] PREPARATION, PROPERTIES, AND CHARACTERIZATION OF METHANESULFONATO COMPLEXES OF ARSENIC(III), ANTIMONY(III), AND BISMUTH(III)
KAPOOR, R
WADHAWAN, P
KAPOOR, P
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (06): : 1195 - 1199
[25] DIHALOGENO(N,N-DIETHYLDITHIOCARBAMATO)-ARSENIC(III), ANTIMONY(III) AND BISMUTH(III)
CRAS, JA
VANDELEEMPUT, PJHAM
WILLEMSE, J
BOSMAN, WP
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1977, 96 (03): : 78 - 80
[26] Preparation and characterization of mixed glycolate-salicylaldiminate derivatives of antimony(III)
Goyal, S
Singh, A
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (12): : 1302 - 1306
[27] Thiolates of arsenic(III), antimony(III), and bismuth(III) with DL-α-dihydrolipoic acid
Ioannou, Panayiotis V.
Tsivgoulis, Gerasimos M.
MONATSHEFTE FUR CHEMIE, 2014, 145 (06): : 897 - 909
[28] SEPARATE AMPEROMETRIC DETERMINATION OF ARSENIC(III) AND ANTIMONY(III) WITH POTASSIUM IODATE
CHOKINA, NY
SONGINA, OA
ZAKHAROV, VA
JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1979, 34 (02): : 241 - 245
[29] Alkoxo-Bridged Heterobinuclear Derivatives of Arsenic(III) and Boron Based on Dithiophosphate Ligands: Synthesis and Characterization
Sharma, Pankaj Kumar
Singh, Yashpal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (02) : 471 - 479
[30] Arsenic(III), but not antimony(III), induces DNA-protein crosslinks
Gebel, T
Birkenkamp, P
Luthin, S
Dunkelberg, H
ANTICANCER RESEARCH, 1998, 18 (6A) : 4253 - 4257

← 1 2 3 4 5 →