Stereoselective synthesis of the C9-C19 lactone-dipropionate fragment of calyculin C

被引：6
|
作者：
Karisalmi, K [1 ]
Koskinen, AMP [1 ]
机构：
[1] Helsinki Univ Technol, Organ Chem Lab, FIN-02015 Helsinki, Finland
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 44期
基金：
芬兰科学院;
关键词：
aldol reactions; crotylation; diastereoselectivity; natural products; stereoselective synthesis;
D O I：
10.1016/j.tetlet.2004.09.012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly diastereoselective synthesis of the title fragment of calyculin C has been developed based on an internal asymmetric induction between a chiral aldehyde and Z-crotyl trifluorosilane. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8245 / 8248
页数：4
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