The Solubility Parameters of Ionic Liquids

被引:104
|
作者
Marciniak, Andrzej [1 ]
机构
[1] Warsaw Univ Technol, Dept Phys Chem, Fac Chem, PL-00664 Warsaw, Poland
关键词
ionic liquid; Hildebrand's solubility parameter; standard enthalpy of vaporization; INFINITE DILUTION MEASUREMENTS; INVERSE GAS-CHROMATOGRAPHY; ACTIVITY-COEFFICIENTS; ORGANIC SOLUTES; COMPOSITION DEPENDENCE; INTERNAL ENERGIES; BINARY-MIXTURES; TEMPERATURE; WATER; VAPORIZATION;
D O I
10.3390/ijms11051973
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The Hildebrand's solubility parameters have been calculated for 18 ionic liquids from the inverse gas chromatography measurements of the activity coefficients at infinite dilution. Retention data were used for the calculation. The solubility parameters are helpful for the prediction of the solubility in the binary solvent mixtures. From the solubility parameters, the standard enthalpies of vaporization of ionic liquids were estimated.
引用
收藏
页码:1973 / 1990
页数:18
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