ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

被引：55
|
作者：
Sha, Ye [1 ]
Rahman, Md Anisur [1 ]
Zhu, Tianyu [1 ]
Cha, Yujin [1 ]
McAlister, C. Wayne [1 ]
Tang, Chuanbing [1 ]
机构：
[1] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
来源：
CHEMICAL SCIENCE | 2019年 / 10卷 / 42期
基金：
美国国家科学基金会;
关键词：
MICELLAR MORPHOLOGIES; DIBLOCK COPOLYMERS; NANOPARTICLES; PISA; MECHANOCHEMISTRY; METALLOPOLYMERS; ARCHITECTURES; HOMOPOLYMERS; POLYMERS; ATRP;
D O I：
10.1039/c9sc03056e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.
引用
收藏
页码：9782 / 9787
页数：6
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