A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

被引：6
|
作者：
Yang, Xuejin [1 ]
Murphy, Laura M. [2 ]
Haque, Farihah M. [3 ,4 ]
Grayson, Scott M. [3 ]
Boydston, Andrew J. [1 ,5 ]
机构：
[1] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA
[2] Univ Washington Tacoma, Sch Integrated Arts & Sci, Div Sci & Math, Tacoma, WA 98402 USA
[3] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
[4] Univ Minnesota, Dept Chem, 207 Pleasant St SE, Minneapolis, MN 55455 USA
[5] Univ Wisconsin, Dept Chem & Biol Engn, Dept Mat Sci & Engn, Madison, WI 53706 USA
来源：
POLYMER CHEMISTRY | 2021年 / 12卷 / 19期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1039/d1py00191d
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We have achieved breakthroughs for the efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP). Molecular weight control from 1 to 16 kDa can be targeted in a straightforward manner. Assisted by this method, the T-g-M-n dependence of linear pDCPD is investigated and reported for the first time.
引用
收藏
页码：2860 / 2867
页数：8
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