A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

被引：6

作者：

Yang, Xuejin ^{[1
]}

Murphy, Laura M. ^{[2
]}

Haque, Farihah M. ^{[3
,4
]}

Grayson, Scott M. ^{[3
]}

Boydston, Andrew J. ^{[1
,5
]}

机构：

[1] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA

[2] Univ Washington Tacoma, Sch Integrated Arts & Sci, Div Sci & Math, Tacoma, WA 98402 USA

[3] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

[4] Univ Minnesota, Dept Chem, 207 Pleasant St SE, Minneapolis, MN 55455 USA

[5] Univ Wisconsin, Dept Chem & Biol Engn, Dept Mat Sci & Engn, Madison, WI 53706 USA

来源：

POLYMER CHEMISTRY | 2021年 / 12卷 / 19期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/d1py00191d

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We have achieved breakthroughs for the efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP). Molecular weight control from 1 to 16 kDa can be targeted in a straightforward manner. Assisted by this method, the T-g-M-n dependence of linear pDCPD is investigated and reported for the first time.

引用

页码：2860 / 2867

页数：8

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