Rapid catalytic oxygenation of hydrocarbons with perhalogenated ruthenium porphyrin complexes

被引：0

作者：

Groves, JT ^{[1
]}

Shalyaev, KV ^{[1
]}

Bonchio, M ^{[1
]}

Carofiglio, T ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

3RD WORLD CONGRESS ON OXIDATION CATALYSIS | 1997年 / 110卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Perhalogenated ruthenium porphyrins were found to be efficient catalysts for the oxygenation of hydrocarbons including secondary alkanes and benzene in the presence of 2,6-dichloropyridine N-oxide under mild conditions in aprotic media. Up to 15,000 turnovers and rates of 800 TO/min were obtained. A mechanism where Ru(III) - Ru(V) intermediates play an important role is proposed and discussed.

引用

页码：865 / 872

页数：8

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