Synthesis of heteroaromatic carboxylic acids by carbonylation of hetaryl halides with catalysts based on cobalt carbonyl modified with epoxides

被引:5
|
作者
Boyarskii, V. P. [1 ]
Zhesko, T. E.
Larionov, E. V.
Polukeev, V. A.
机构
[1] VNIIneftekhim Open Joint Stock Co, St Petersburg, Russia
[2] NPF Gallar Ltd Liabil Co, St Petersburg, Russia
[3] St Petersburg State Univ, St Petersburg 198904, Russia
[4] Vekton Private Co, St Petersburg 198904, Russia
关键词
Carbonylation;
D O I
10.1134/S1070427207040106
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new method for the synthesis of heteroaromatic acids and their derivatives (esters and salts) by carbonylation of the corresponding halides was developed. Hetaryl halides were activated in alcoholic-alkali medium by highly active catalytic systems based on cobalt carbonyl modified with epoxides, developed previously for carbonylation of aryl halides.
引用
收藏
页码:571 / 575
页数:5
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