Synthesis and structure of Cs[UO2(SeO4)(OH)] • nH2O (n=1.5 or 1)

被引：3

作者：

Serezhkina, L. B. ^{[1
]}

Peresypkina, E. V. ^{[2
]}

Virovets, A. V. ^{[2
]}

Pushkin, D. V. ^{[1
]}

Verevkin, A. G. ^{[1
]}

机构：

[1] Samara State Univ, Samara 443011, Russia

[2] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

CRYSTALLOGRAPHY REPORTS | 2010年 / 55卷 / 03期

关键词：

CRYSTAL-STRUCTURES;

D O I：

10.1134/S1063774510030041

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and single-crystal X-ray diffraction study of Cs[UO2(SeO4)(OH)] center dot 1.5H(2)O (I) and Cs[UO2(SeO4)(OH)] center dot H2O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) , b = 14.4942(4) , c = 8.9270(3) , beta = 112.706(1)A degrees, space group P2(1)/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) , b = 11.5358(3) , c = 9.5565(2) , beta = 113.273(1)A degrees, space group P2(1)/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO2(SeO4)(OH)](-) layers which belong to the AT (3) M (2) crystal chemical group of uranyl complexes (A = UO (2) (2+) , T (3) = SeO4 (2-), and M (2) = OH-). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands.

引用

页码：381 / 385

页数：5

共 50 条

[21] Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] • 1.33H2O
Medrish, I. V.
Peresypkina, E. V.
Virovets, A. V.
Serezhkina, L. B.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (08) : 629 - 634
[22] Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4)] · 1.33H2O
I. V. Medrish
E. V. Peresypkina
A. V. Virovets
L. B. Serezhkina
Russian Journal of Coordination Chemistry, 2008, 34 : 629 - 634
[23] Structure and some properties of [UO2(SeO4)(C5H12N2O)2(H2O)]
L. B. Serezhkina
E. V. Peresypkina
A. V. Virovets
E. V. Grechishnikova
A. V. Savchenkov
Russian Journal of Inorganic Chemistry, 2011, 56 : 1739 - 1746
[24] Structure and some properties of [UO2(SeO4)(C5H12N2O)2(H2O)]
Serezhkina, L. B.
Peresypkina, E. V.
Virovets, A. V.
Grechishnikova, E. V.
Savchenkov, A. V.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (11) : 1739 - 1746
[25] Vibrational spectra of Cs2Cu(SO4)2•6H2O and Cs2Cu(SeO4)2•nH2O (n=4, 6) with a crystal structure determination of the Tutton salt CS2CU(SeO4)2•6H2O
Wildner, M.
Marinova, D.
Stoilova, D.
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1106 : 440 - 451
[26] Supramolecular templates for the synthesis of new nanostructured uranyl compounds: Crystal structure of [NH3(CH2) 9NH3][(UO2)(SeO4)(SeO 2OH)](NO3)
Gurzhiy V.V.
Krivovichev S.V.
Burns P.C.
Tananaev I.G.
Myasoedov B.F.
Radiochemistry, 2010, 52 (1) : 1 - 6
[27] Synthesis and study of uranyl phosphates (UO2) 3(PO4)2·nH2O
Chernorukov N.G.
Nipruk O.V.
Knyazev A.V.
Pykhova Yu.P.
Radiochemistry, 2010, 52 (2) : 133 - 137
[28] Synthesis and crystal structures of α- and β-Mg2[(UO2)3(SeO4)5](H2O)16
Krivovichev, SV
Kahlenberg, V
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (15): : 2736 - 2742
[29] Vibrational spectra of Cs2Cu(SO4)2•6H2O and Cs2Cu(SeO4)2•nH2O (n = 4, 6) with a crystal structure determination of the Tutton salt Cs2Cu(SeO4)2•6H2O (vol 1106, pg 440, 2016)
Wildner, M.
Marinova, D.
Stoilova, D.
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1116 : 340 - 340
[30] Crystal structure of Cs[(UO2)2(C2O4)2(OH)] • H2O
Serezhkina, L. B.
Peresypkina, E. V.
Virovets, A. V.
Medrish, I. V.
Pushkin, D. V.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (10) : 1577 - 1580

← 1 2 3 4 5 →