FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O

被引：7
|
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 01期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy; SPECTRA;
D O I：
10.1007/s10947-010-0014-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of the interaction products of (NH4)(2)[Ru(NO)Cl-5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)(3)(H2O)Cl][Ru(NO)(NH3)(3)(OH)Cl] x [Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) angstrom, b = 8.202(2) angstrom, c = 11.844(2) angstrom; beta = 101.54(3)degrees.
引用
收藏
页码：99 / 106
页数：8
相关论文
共 50 条
  • [21] Crystal structure of {[Pd(NH3)4]3[Pd(NH3)3Cl]2}Cl8
    Gromilov, SA
    Baidina, IA
    Tatarchuk, VV
    Virovets, AV
    Druzhinina, IA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 40 (04) : 629 - 632
  • [22] Crystal structure of [Pd(NH3)4]3[Pd(NH3)3Cl]2 Cl8
    S. A. Gromilov
    I. A. Baidina
    V. V. Tatarchuk
    A. V. Virovets
    I. A. Druzhinina
    Journal of Structural Chemistry, 1999, 40 : 629 - 632
  • [23] Synthesis and crystal structure of nitrosoruthenium triammino complex [RuNO(NH3)3Cl(H2O)]Cl2
    Emel'yanov, VA
    Baidina, IA
    Gromilov, SA
    Vasiliev, AD
    Belyaev, AV
    JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (06) : 1030 - 1034
  • [24] CRYSTAL-STRUCTURE OF NITROSORUTHENIUM AND NITROSOOSMIUM BICOMPLEXED COMPOUNDS [RU(NO)(NH3)4CL][RU(NO)(NO2)4(OH)] AND [RU(NO)(NH3)4OH][OS(NO)(NO2)4(OH)].0,5H2O
    SALOMOV, AS
    PARPIEV, NA
    SHARIPOV, KT
    KOKUNOVA, VN
    SINITSYN, NM
    PORAIKOSHITS, MA
    ZHURNAL NEORGANICHESKOI KHIMII, 1984, 29 (11): : 2853 - 2864
  • [25] Synthesis and Crystal Structure of Nitrosoruthenium Triammino Complex [RuNO(NH3)3Cl(H2O)]Cl2
    V. A. Emel'yanov
    I. A. Baidina
    S. A. Gromilov
    A. D. Vasiliev
    A. V. Belyaev
    Journal of Structural Chemistry, 2000, 41 : 1030 - 1034
  • [26] Metal ampoules as mini-autoclaves:: Syntheses and crystal structures of [Al(NH3)4Cl2][Al(NH3)2Cl4] and (NH4)2[Al(NH3)4Cl2][Al(NH3)2Cl4]Cl2
    Bremm, S
    Meyer, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (03): : 407 - 410
  • [27] STRUCTURAL CHARACTERIZATION OF TRANS-[CR(NH3)4(H2O)CL]CL2 AND TRANS-[CR(NH3)4CL2]L
    BRENCIC, JV
    LEBAN, I
    ZULE, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 521 (02): : 199 - 206
  • [28] Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4aEuro¢H2O
    Makhinya, A. N.
    Il'in, M. A.
    Baidina, I. A.
    Korol'kov, I. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 57 (06) : 1182 - 1187
  • [29] ISONICOTINAMIDE AS ENTERING LIGAND ON TRANS-[RU(NH3)4P(OME)3(H2O)]2+, TRANS-[RU(NH3)4P(OPR)3(H2O)]2+, TRANS-[RU(NH3)4P(OIPR)3(H2O)]2+, TRANS-[RU(NH3)4P (OBU)3(H2O)]2+
    DONASCIMENTO, JC
    FRANCO, DW
    INORGANICA CHIMICA ACTA, 1986, 113 (01) : 55 - 60
  • [30] ELECTRONIC AND GEOMETRIC STRUCTURES OF PT(NH3)22+, PT(NH3)2CL2, PT(NH3)3X, AND PT(NH3)2XY (X,Y=H2O,OH-)
    BASCH, H
    KRAUSS, M
    STEVENS, WJ
    COHEN, D
    INORGANIC CHEMISTRY, 1985, 24 (21) : 3313 - 3317
12345