FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O

被引：7
|
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 01期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy; SPECTRA;
D O I：
10.1007/s10947-010-0014-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of the interaction products of (NH4)(2)[Ru(NO)Cl-5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)(3)(H2O)Cl][Ru(NO)(NH3)(3)(OH)Cl] x [Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) angstrom, b = 8.202(2) angstrom, c = 11.844(2) angstrom; beta = 101.54(3)degrees.
引用
收藏
页码：99 / 106
页数：8
相关论文
共 50 条
  • [1] First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2010, 51 : 99 - 106
  • [2] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (06) : 1090 - 1097
  • [3] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl·H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2008, 49 : 1090 - 1097
  • [4] Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O
    V. A. Emel’yanov
    I. A. Baidina
    M. A. Il’in
    S. A. Gromilov
    Journal of Structural Chemistry, 2006, 47 : 380 - 382
  • [5] Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl•H2O
    Emel'yanov, V. A.
    Baidina, I. A.
    Il'in, M. A.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 47 (02) : 380 - 382
  • [6] [Ru(NH3) 6](MoO4) Cl•3H2O AND [M(NH3)6](ReO4)3•2H2O (M = Ru, Ir). SYNTHESIS AND CRYSTAL STRUCTURE
    Khranenko, S. P.
    Bykova, E. A.
    Yusenko, K. V.
    Tyutyunnik, A. P.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (05) : 931 - 936
  • [7] [Ru(NH3)6](MoO4)Cl·3H2O and [M(NH3)6](ReO4)3·2H2O (M = Ru, Ir). Synthesis and crystal structure
    S. P. Khranenko
    E. A. Bykova
    K. V. Yusenko
    A. P. Tyutyunnik
    S. A. Gromilov
    Journal of Structural Chemistry, 2013, 54 : 931 - 936
  • [8] Cellular effects of transferrin coordinated to [Cl(NH3)5Ru]Cl2 and cis-[Cl2(NH3)4Ru]Cl
    Frasca, DR
    Gehrig, LE
    Clarke, MJ
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2001, 83 (2-3) : 139 - 149
  • [9] STRUCTURE OF THE FIRST NITROSOAMMINE COMPLEXES OF RUTHENIUM WITH A COORDINATED SULFATE ION: [Ru(NO)(NH3)4(SO4)](HSO4)•H2O AND [Ru(NO)(NH3)3Cl(SO4)]•2H2O
    Makhinya, A. N.
    Shusharina, E. A.
    Baidina, I. A.
    Il'in, M. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (05) : 946 - 953
  • [10] Synthesis and Crystal Structure of [Pd(NH3)4]Cl2·2[Pd(NH3)3Cl]Cl
    Pei Feng XING
    Peng Ji ZHAO
    Rui Liang HUANG
    Ze Ning HUANG (Southwest Institute of Nuclear Physics and Chemistry
    Hong LIANG
    Zhi Guang QIAN (Institute of Chemistry
    Chinese Chemical Letters, 1997, (03) : 259 - 262
12345