Chlorido(η5-pentamethylcyclopentadienyl)-(1,10-phenanthroline-k2N,N′) iridium(III) trifluoromethanesulfonate

被引：7
|
作者：
Scharwitz, Michael [1 ]
Schaefer, Sven [1 ]
van Almsick, Tobias [1 ]
Sheldrick, William S. [1 ]
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
CARBONYL-COMPOUNDS; COMPLEXES; WATER;
D O I：
10.1107/S1600536807011750
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The cation of the title compound, [Ir(eta(5) - C5Me5)Cl(C12H8N2)]-CF3SO3, contains a half-sandwich (eta(5)-C5Me5)Ir-III fragment coordinated in a kappa N-2 manner by the N atoms of a 1,10-phenanthroline ligand. The diimine ligand is inclined at an angle of 62.6 (4)degrees to the plane of the pentamethylcyclopentadienyl ligand.
引用
收藏
页码：M1111 / M1113
页数：3
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