Synthesis of amphiphilic polyelectrolyte block copolymers using "living" radical polymerization. Application as stabilizers in emulsion polymerization

被引:0
|
作者
Bouix, M
Gouzi, J
Charleux, B
Vairon, JP
Guinot, P
机构
[1] Univ Paris 06, Lab Chim Macromol, F-75252 Paris 05, France
[2] CERD Elf Atochem, F-27470 Serquigny, France
关键词
D O I
10.1002/(SICI)1521-3927(19980401)19:4<209::AID-MARC209>3.0.CO;2-S
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper describes the synthesis of amphiphilic block copolymers composed of an ionic poly(styrenesulfonate) first segment and a hydrophobic polystyrene second one, using TEMPO-mediated "living" radical polymerization. These copolymers proved to be efficient stabilizers in the emulsion polymerization of styrene.
引用
收藏
页码:209 / 213
页数:5
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