Quasi-classical rate constants for the inelastic process O2(υi>>1)+O2→O2(υf)+O2

被引：0
|
作者：
Campos-Martinez, J
Carmona-Novillo, E
Echave, J
Hernandez, MI
Palma, J
机构：
[1] CSIC, Inst Matemat & Fis Fundamental, E-28006 Madrid, Spain
[2] Univ Nacl Quilmes, Ctr Estudios & Invest, Bernal, Argentina
来源：
MOLECULAR PHYSICS | 2000年 / 98卷 / 21期
关键词：
D O I：
10.1080/00268970009483377
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rate constants have been calculated using quasi-classical trajectories (QCT) for the vibrational relaxation of highly excited O-2: O-2(X (3)Sigma (-)(g), nu (i)) + O-2(X (3)Sigma (-)(g), 0) --> O-2(X (3)Sigma (-)(g), nu (f)) + O-2(X (3)Sigma (-)(g)), with 22 less than or equal to nu (i) less than or equal to 28. The present full-dimensional QCT results agree very well with recent quantum reduced dimensionality calculations, giving further support to the hypothesis that the observed experimental jump in depletion rates would be due partially to enhanced vibrational relaxation.
引用
收藏
页码：1729 / 1735
页数：7
相关论文
共 50 条
  • [31] A comparative study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O
    Tu, Yaojie
    Yang, Wenming
    Siah, Keng Boon
    Prabakaran, Subbaiah
    INNOVATIVE SOLUTIONS FOR ENERGY TRANSITIONS, 2019, 158 : 1473 - 1478
  • [32] Heterogeneous quenching of O2(1Δg) in H2:O2 mixture
    Klopovskiy, KS
    Lopaev, DV
    Popov, NA
    Rakhimov, AT
    Rakhimova, TV
    INTERNATIONAL CONFERENCE ON PHENOMENA IN IONIZED GAS, VOL I, PROCEEDINGS, 1999, : 9 - 10
  • [33] A FRONTIER ORBITAL INVESTIGATION OF THE MECHANISM OF EPOXIDATION OF ALKENES USING [CRO(O2)2, [MOO(O2)2, [WO(O2)2
    JORGENSEN, KA
    HOFFMANN, R
    ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1986, 40 (06): : 411 - 419
  • [34] Disodium bis[μ-2-hydroxy-2-methyl-propanoato(2-)]-O1,O2 :O2;O2:O1,O2-bis-[dioxovanadate(V)] heptahydrate
    Bourne, SA
    Cruywagen, JJ
    Kleinhorst, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 2002 - 2004
  • [35] RATE CONSTANTS OF O2(1-DELTA-G)
    RAJA, N
    ARORA, PK
    CHATHA, JPS
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1986, 18 (04) : 505 - 512
  • [36] Waiting for O2
    Zahnle, Kevin
    Catling, David
    EARTH'S EARLY ATMOSPHERE AND SURFACE ENVIRONMENT, 2014, 504 : 37 - 48
  • [37] 蓝色O2
    李孟妍
    新作文(小学中高年级版), 2003, (Z6) : 125 - 125
  • [38] The Nutcracker at The O2
    不详
    DANCING TIMES, 2011, 101 (1213): : 7 - 7
  • [39] PARAMAGNETISM OF O2
    LETHBRIDGE, JW
    DAVIES, MB
    JOURNAL OF CHEMICAL EDUCATION, 1973, 50 (09) : 656 - 656
  • [40] O2 to the Rescue
    Speece, Richard E.
    Clidence, David
    Neal, Larry
    Moorer, Hope
    Bailey, William
    CIVIL ENGINEERING, 2016, 86 (7-8): : 68 - +
12345