Covalent organic frameworks for environmental analysis

被引:57
|
作者
Qian, Hai-Long [1 ,2 ,3 ]
Wang, Yan [3 ]
Yan, Xiu-Ping [1 ,2 ,3 ]
机构
[1] Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi 214122, Jiangsu, Peoples R China
[2] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China
[3] Jiangnan Univ, Sch Food Sci & Technol, Inst Analyt Food Safety, Wuxi 214122, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Covalent organic frameworks; Environmental analysis; Adsorption; removal; Separation; Sensing; SOLID-PHASE MICROEXTRACTION; FACILE SYNTHESIS; REMOVAL; CRYSTALLINE; EXTRACTION; IMMOBILIZATION; MICROSPHERES; FABRICATION; ADSORBENTS; ADSORPTION;
D O I
10.1016/j.trac.2021.116516
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
As typical representative of porous crystalline polymers, covalent organic frameworks (COFs) based on dynamic covalent chemistry and topological design are constructed with organic units via covalent bond. Their unique properties such as high stability, accessible functionality, ordered porosity, and predesignable structure make COFs highly promising in environmental analysis. This review highlights the state-of-the-art design and modification of COFs in terms of functionality, stability and pore to meet the requirements of environmental analysis, as well as the mechanism and application of the COFs for the adsorption/removal, separation and sensing of various environmental contaminants. In addition, the challenge and future direction of COFs in environmental analysis are outlooked for the further research. (c) 2022 Elsevier B.V. All rights reserved.
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页数:16
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