A Comparison of Functional Fillers-Greenhouse Gas Emissions and Air Pollutants from Lignin-Based Filler, Carbon Black and Silica

The transformation from a fossil-based economy to a sustainable and circular bioeconomy is urgently needed to achieve the climate targets of the Paris Agreement, reduce air pollution and ensure a long-term competitive economy. Due to its carbonaceous and aromatic basic components, lignin has the potential for material valorization within bioeconomy. So far, lignin produced in the pulp and paper industry has mainly been used internally to generate thermal process energy, as it is difficult to extract it from biomass in a pure and unaltered form. The valorization of lignin to improve the economics of pulp mills is a current aim of the industry. Hydrothermal treatment (HTT) of a partial flow from the lignin stream to produce a functional filler for use in polymer blends is one valorization option. The environmental assessment of the lignin-based HTT filler, conducted using life cycle assessment (LCA), shows that substitution of the conventional fillers carbon black and silica could be associated with significant reductions in greenhouse gas emissions and air pollutants. Depending on the allocation methodology and the reference filler considered, approx. 5 kg CO2 eq./kg filler, 80-93% SO2 emissions, 27-79% PM emissions, and 88-98% PAH emissions can be saved.