A facile synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate: Ceria based catalysts

被引：1
|
作者：
Venkatesh [1 ,2 ,3 ]
Shamshuddin, Sathgatta Zaheeruddin Mohamed [1 ,2 ]
Pratap, Srinivasa Raghavendra [1 ,2 ,3 ]
机构：
[1] HMS Inst Technol, Chem Res Lab, NH4, Tumakuru, Karnataka, India
[2] Bharathiar Univ, Res & Dev Ctr, Coimbatore, Tamil Nadu, India
[3] Channabasaveshwara Inst Technol, Gubbi, India
来源：
JOURNAL OF THE MEXICAN CHEMICAL SOCIETY | 2018年 / 62卷 / 04期
关键词：
Glycerol; Ceria/Zirconia/Magnesia; Glycerol carbonate; Transesterification; HETEROGENEOUS CATALYST; CARBONYLATION; CEO2; ACID; DEHYDRATION; ZEOLITES; CO2;
D O I：
10.29356/jmcs.v62i4.859
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solid base catalysts such as Ceria-Zirconia-Magnesia with different mole ratio of magnesium were prepared by impregnation method and characterized by CO2-TPD, PXRD, FT-IR and ICP-OES analysis. The catalytic activity of the catalysts was tested in the liquid phase transesterification of glycerol with dimethyl carbonate to synthesise glycerol carbonate. Optimization of reaction condition was carried out by varying the molar ratio of the reactants, temperature and time. The highest yield (97 %) of glycerol carbonate was obtained at a reactant molar ratio of 1:3 at 120 degrees C in 6 h. Study of reusability and reactivation of solid base catalyst was also taken up. A suitable base catalysed mechanism for the formation of glycerol carbonate is proposed.
引用
收藏
页码：148 / 159
页数：12
相关论文
共 50 条
  • [1] Synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate over MgAl mixed oxide catalysts
    Liu, Peng
    Derchi, Margherita
    Hensen, Emiel J. M.
    [J]. APPLIED CATALYSIS A-GENERAL, 2013, 467 : 124 - 131
  • [2] Synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate over Mg/Al/Zr catalysts
    Malyaadri, M.
    Jagadeeswaraiah, K.
    Prasad, P. S. Sai
    Lingaiah, N.
    [J]. APPLIED CATALYSIS A-GENERAL, 2011, 401 (1-2) : 153 - 157
  • [3] Transesterification of glycerol and dimethyl carbonate to glycerol carbonate over mixed metal oxide catalysts
    Li Yajin
    He, Dehua
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [4] Continuous Synthesis of Glycerol Carbonate by Transesterification of Glycerol with Dimethyl Carbonate Over Fe–La Mixed Oxide Catalysts
    Piyusa P. Pattanaik
    P. Mahesh Kumar
    N. Raju
    N. Lingaiah
    [J]. Catalysis Letters, 2021, 151 : 1433 - 1443
  • [5] LTA zeolites as catalysts for transesterification of glycerol with dimethyl carbonate
    Kowalska-Kus, J.
    Held, A.
    Nowinska, K.
    Gora-Marek, K.
    [J]. FUEL, 2024, 362
  • [6] KF/MgO catalyzed transesterification of glycerol and dimethyl carbonate to glycerol carbonate
    Chen D.
    Zhu J.
    Wu Q.
    Wang Z.
    Zhang J.
    [J]. Huagong Jinzhan/Chemical Industry and Engineering Progress, 2022, 41 (04): : 2082 - 2089
  • [7] Transesterification of Glycerol with Dimethyl Carbonate to Glycerol Carbonate over Na-Based Zeolites
    Pan Saiyong
    Zheng Liping
    Nie Renfeng
    Xia Shuixin
    Chen Ping
    Hou Zhaoyin
    [J]. CHINESE JOURNAL OF CATALYSIS, 2012, 33 (11) : 1772 - 1777
  • [8] Continuous Synthesis of Glycerol Carbonate by Transesterification of Glycerol with Dimethyl Carbonate Over Fe-La Mixed Oxide Catalysts
    Pattanaik, Piyusa P.
    Kumar, P. Mahesh
    Raju, N.
    Lingaiah, N.
    [J]. CATALYSIS LETTERS, 2021, 151 (05) : 1433 - 1443
  • [9] Transesterification of glycerol with dimethyl carbonate for the synthesis of glycerol carbonate over Mg/Zr/Sr mixed oxide base catalysts
    Parameswaram, G.
    Srinivas, M.
    Babu, B. Hari
    Prasad, P. S. Sai
    Lingaiah, N.
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (12) : 3242 - 3249
  • [10] Glycerol transesterification with dimethyl carbonate using nano alumina based catalysts
    Nebahat, Degirmenbasi
    Nezahat, Boz
    [J]. RESEARCH JOURNAL OF BIOTECHNOLOGY, 2015, 10 (08): : 26 - 34
12345