Transesterification of Glycerol with Dimethyl Carbonate to Glycerol Carbonate over Na-Based Zeolites

被引：67

作者：

Pan Saiyong ^{[1
]}

Zheng Liping ^{[1
]}

Nie Renfeng ^{[1
]}

Xia Shuixin ^{[1
]}

Chen Ping ^{[1
]}

Hou Zhaoyin ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Inst Catalysis, Hangzhou 310028, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF CATALYSIS | 2012年 / 33卷 / 11期

基金：

中国国家自然科学基金;

关键词：

glycerol carbonate; glycerol; dimethyl carbonate; zeolite; NaY; transesterification; SELECTIVE OXIDATION; CATALYZED SYNTHESIS; HYDROGENOLYSIS; CARBONYLATION; ETHERIFICATION; CONVERSION; CHEMICALS; EFFICIENT; DIOXIDE; BIOMASS;

D O I：

10.1016/S1872-2067(11)60450-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Glycerol carbonate (GC) was synthesized via transesterification of glycerol with dimethyl carbonate under mild conditions over a series of base zeolites. It was found that the NaY zeolite exhibited a higher selectivity for GC (100%) than heterogeneous bases (such as CaO and SrO) or homogeneous catalysts (such as NaOH and K2CO3). Further experiments over different base zeolites disclosed that this transesterification reaction depended strongly on catalyst structure. Base zeolites with small pore diameter such as 3A, 4A, and NaZSM-5 were inactive, while NaY and Na beta with larger pore diameter exhibited excellent GC yields under mild conditions.

引用

页码：1772 / 1777

页数：6

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