Thermo-oxidative degradation of novel epoxy containing silicon and phosphorous nanocomposites

被引：47
|
作者：
Chiang, CL
Ma, CCM [1 ]
Wang, FY
Kuan, HC
机构：
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30043, Taiwan
[2] Hung Kuang Inst Technol, Dept Ind Safety & Hlth, Shalu 433, Taiwan
[3] Cheg Shiu Ind Technol, Dept Chem Engn, Kaohsiung 833, Taiwan
来源：
EUROPEAN POLYMER JOURNAL | 2003年 / 39卷 / 04期
关键词：
epoxy; nanocomposite; thermo-oxidative degradation; flame retardance; activation energy; silicon; phosphorous;
D O I：
10.1016/S0014-3057(02)00283-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Modified epoxy nanocomposites containing silicon and phosphorous was prepared and compared with pure epoxy. The study of thermo-oxidative degradation of modified epoxy nanocomposites and pure epoxy has been utilized by thermal analysis. The thermal stability of modified epoxy nanocomposites is not superior to that of the pure epoxy at low temperature, however, the char yield of modified epoxy nanocomposites is higher than that of the pure epoxy at 800 degreesC in air atmosphere. The modified epoxy nanocomposites possess better thermal stability at high temperature range. The values of the limiting oxygen index of pure epoxy and modified epoxy nanocomposites are 24 and 32, respectively. This indicates that modified epoxy nanocomposites possesses better flame retardance. By the Kissinger's method, the activation energies of thermo-oxidative degradation for epoxy nanocomposites are less than those of thermo-oxidative degradation for pure epoxy in first stage of thermo-oxidative degradation. However, the activation energies of thermo-oxidative degradation for epoxy nanocomposites are more than those of thermo-oxidative degradation for pure epoxy in second stage of thermo-oxidative degradation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：825 / 830
页数：6
相关论文
共 50 条
  • [41] Thermo-Oxidative Degradation Behavior of Recycled Polypropylene
    Nasir, Asad
    Yasin, Tariq
    Islam, Atif
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 119 (06): : 3315 - 3320
  • [42] Thermo-oxidative stability of polypropylene/layered silicate nanocomposites
    Dominkovics, Zita
    Jozsef Hari
    Fekete, Erika
    Pukanszky, Bela
    [J]. POLYMER DEGRADATION AND STABILITY, 2011, 96 (04) : 581 - 587
  • [43] Crystallization and melting behavior of PP/CaCO3 nanocomposites during thermo-oxidative degradation
    Wang, Yuhai
    Shen, Hao
    Li, Gu
    Mai, Kancheng
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 100 (03) : 999 - 1008
  • [44] An assessment of the role of morphology in thermal/thermo-oxidative degradation mechanism of PP/EVA/clay nanocomposites
    Goodarzi, Vahabodin
    Jafari, Seyed Hassan
    Khonakdar, Hossein Ali
    Monemian, Seyed Ali
    Mortazavi, Mehdi
    [J]. POLYMER DEGRADATION AND STABILITY, 2010, 95 (05) : 859 - 869
  • [45] Thermo-oxidative degradation of graphite/epoxy composite laminates: Modeling and long-term predictions
    Ozcelik, O.
    Aktas, L.
    Altan, M. C.
    [J]. EXPRESS POLYMER LETTERS, 2009, 3 (12): : 797 - 803
  • [46] Kinetics of thermo-oxidative degradation of polypropylene/aluminum trihydroxide/organo Fe-montmorillonite nanocomposites
    Kong, Qinghong
    Hu, Yuan
    Song, Lei
    Tang, Yuwen
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 104 (03) : 1145 - 1151
  • [47] Kinetics of thermo-oxidative degradation of polypropylene/aluminum trihydroxide/organo Fe-montmorillonite nanocomposites
    Qinghong Kong
    Yuan Hu
    Lei Song
    Yuwen Tang
    [J]. Journal of Thermal Analysis and Calorimetry, 2011, 104 : 1145 - 1151
  • [48] Crystallization and melting behavior of PP/CaCO3 nanocomposites during thermo-oxidative degradation
    Yuhai Wang
    Hao Shen
    Gu Li
    Kancheng Mai
    [J]. Journal of Thermal Analysis and Calorimetry, 2010, 100 : 999 - 1008
  • [49] THERMAL AND THERMO-OXIDATIVE DEGRADATION OF POLYSTYRENE IN THE PRESENCE OF BROMINE-CONTAINING FLAME RETARDANTS
    DAUENGAUER, SA
    UTKINA, OG
    SAZANOV, YN
    [J]. JOURNAL OF THERMAL ANALYSIS, 1988, 33 (04): : 1213 - 1219
  • [50] Thermal and thermo-oxidative degradation of polystyrene in the presence of bromine-containing flame retardants
    Dauengauer, S.A.
    Utkina, O.G.
    Sazanov, Yu.N.
    [J]. Journal of thermal analysis, 1988, 33 (04): : 1213 - 1219
12345