Crystal structures of (Ph4P)2[HfCl6]•2CH2Cl2 and (Ph4P)2[Hf2Cl10]•CH2Cl2

被引：12

作者：

Neumüller, B ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 15期

关键词：

hafnium; chlorohafnates; crystal structures;

D O I：

10.1002/zaac.200400370

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Colourless single crystals of (Ph4P)(2)[HfCl6](.)2CH(2)Cl(2) (1) and (Ph4P)(2)[Hf2Cl10](CH2Cl2)-C-. (2) were obtained from hafniumtetra-chloride and tetraphenylphosphonium chloride in dichloromethane solution, using the corresponding stoichiometry of the educts. Both compounds were characterized by X-ray structure determinations. 1: Space group P (1) over tilde, Z = 1, lattice dimensions at 193 K: a = 1018.3(1), b = 1121.0(1), c = 1240.1(1)pm, alpha = 70.55(1)degrees, beta = 81.38(1)degrees, gamma = 80.02(1)degrees, R-1 = 0.0374. 2: Space group P (1) over bar, Z = 1, lattice dimensions at 193 K: a = 1124.4(1), b = 1141.9(1), c = 1281.4(1) pm, alpha = 63.80(1)degrees, beta = 68.15(1)degrees, gamma = 86.33(1)degrees, R-1 = 0.0208.

引用

页码：2576 / 2578

页数：3

共 50 条

[31] Synthesis and characterization of Ni2Cl4(μ-dmpm)2•CH2Cl2, and [NiCl(μ -dmpm)2]Cl, and [NiCl2(μ -dmpm)2]: Crystal structures of Ni2Cl4(μ-dmpm)2•CH2Cl2; NiCl(μ -bdmpm)2]Cl•3H2O; and [NiCl2(μ -dmpm)2]•dmpm = bis(dimethylphosphino)methane
Motta, Austin J.
Kriley, Joseph P.
Majireck, Max
Nogan, Stephen
Jensen, Alexandra
Haskins, Christopher
Lehman, Anna
Haley, Christopher
Groeneman, Ryan H.
Kriley, Charles E.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[32] PREPARATION AND CRYSTAL-STRUCTURE OF (PH4P)2TE4 . 2CH3OH
HUFFMAN, JC
HAUSHALTER, RC
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 518 (11): : 203 - 209
[33] Synthesis and characterization of [Pd2X2(μ-X)2{Ph2P(CH2CH2O)n-CH2CH2PPh2-P,P′}]m (n=3, 5, X = Cl, I) dimetallacrown ethers and the related dinuclear [Pd2Cl2(μ-Cl)2{Ph2P(CH2)12PPh2-P,P′}]m and [Pd2X2(μ-X2){Ph2P(CH2CH2O)2CH2CH3-P)2}] (X = Cl, I) complexes
Smith, DC
Lake, CH
Gray, GM
DALTON TRANSACTIONS, 2003, (14) : 2950 - 2955
[34] On reactions of hexachlorodiberyllate with trimethylsilyl-N-dimethylamide. crystal structures of (Ph4P)3[Be2Cl5(OSiMe3)][BeCl3(Me2NSiMe3)], (Ph4P[BeCl3(HNMe2)], and (Ph4P)(H2NMe2)[BeCl4]
Neumüller, B
Dehnicke, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (01): : 74 - 80
[35] SYNTHESIS AND CRYSTAL-STRUCTURE OF (PPH4)2[MO2(O2C-PH)4CL4].2CH2CL2, A COMPLEX WITH MO=MO BONDING
JANSEN, K
DEHNICKE, K
FENSKE, D
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1987, 42 (09): : 1097 - 1101
[36] REACTION OF TETRASULFURTETRANITRIDE WITH RHENIUM(VII)-CHLORONITRIDE - THE CRYSTAL-STRUCTURE OF "[PH4AS+]2[CL4RE(NS)(NSCL)2-].CH2CL2
ANHAUS, J
SIDDIQI, ZA
ROESKY, HW
BATS, JW
ELERMAN, Y
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1985, 40 (06): : 740 - 744
[37] Reactivity of trans-(CO)3Fe(Ph2Ppym)2 toward metal reagents: Synthesis and crystal structures of [HgCl(Ph2Ppym) (μ-Cl)]2, trans-[(Ph2Ppym)2Rh(CO)Cl]·0.5CH2Cl 2, [PdCl(μ-Ph2Ppym)]2·CH2Cl2,
Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
不详
不详
Inorganica Chimica Acta, 1997, 255 (02): : 239 - 248
[38] The oxochlorotantalates (PPh4)2[Ta2OCl9]2 • 2 CH2Cl2, (PPh4)2[Ta2OCl10] • 2 CH3CN, and (K-18-crown-6)4[Ta4O6Cl12] • 12 CH2Cl2
Noll, A
Müller, U
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (10): : 1721 - 1725
[39] [Ph4P]2[Sb2S15]
Rijnberk, H
Nather, C
Schur, M
Jess, I
Bensch, W
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 920 - 923
[40] THE POLYMERIZATION OF ISOBUTYLENE BY ALCL3 IN CH2CL2 AND THE ROLE OF CH2CL2 IN THE INITIATION REACTION
TOMAN, L
SPEVACEK, J
POKORNY, S
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (03) : 785 - 794

← 1 2 3 4 5 →