Hexaaquazinc(II) 3-ammonionaphthalene-1,5-disulfonate tetrahydrate

被引:1
|
作者
Genther, Dane J.
Squattrito, Philip J.
Kirschbaum, Kristin
Pinkerton, A. Alan [1 ]
机构
[1] Cent Michigan Univ, Dept Chem, Mt Pleasant, MI 48859 USA
[2] Univ Toledo, Dept Chem, Toledo, OH 43606 USA
关键词
D O I
10.1107/S1600536807036938
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Zn(H2O)(6)][H3NC10H5(SO3)(2)](2).4H(2)O (Zn site symmetry 1), is isostructural with its nickel(II) and cobalt(II) analogues. An extensive network of N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds involving the ammonio group, water molecules, and sulfonate O atoms helps to establish the packing. One of the uncoordinated water molecules is disordered over at least two sites (modelled over two positions with site occupancy ratio ca 2: 1).
引用
收藏
页码:M2262 / U166
页数:11
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