Dioxomolybdenum(VI) complexes containing 1-alkyl-2-ethyl-3-hydroxy-4-pyridin-4(1H)-ones

被引：3
|
作者：
Tam, NC
Fletcher, SP
Vogels, CM
Westcott, SA [1 ]
Decken, A
机构：
[1] Mt Allison Univ, Dept Chem, Sackville, NB E4L 1G8, Canada
[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 5A3, Canada
来源：
TRANSITION METAL CHEMISTRY | 2003年 / 28卷 / 01期
关键词：
D O I：
10.1023/A:1022526431113
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dioxomolybdenum(VI) complexes derived from ethyl maltol (2-ethyl-3-hydroxy-4-pyrone) and 1-alkyl-2-ethyl-3-hydroxy-4-pyridin-4(1H)-ones have been prepared and characterized using physical methods including H-1- and C-13- n.m.r. spectroscopy, i.r., elemental analysis, and X-ray diffraction for the pyrone and 3-methylpyridine pyridinone derivatives. The octahedral complexes have the general formula cis-MoO2L2 where L = the deprotonated pyrone or pyridinone ligand.
引用
收藏
页码：103 / 109
页数：7
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