Solvent-Free Microwave Promoted [3+2] Cycloaddition of Alkyne-Azide in Uniform CuO Hollow Nanospheres

被引：21

作者：

Kang, Hyuntae ^{[1
,3
]}

Lee, Hyun Ju ^{[1
,3
]}

Park, Ji Chan ^{[2
]}

Song, Hyunjoon ^{[2
]}

Park, Kang Hyun ^{[1
,3
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[3] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea

来源：

TOPICS IN CATALYSIS | 2010年 / 53卷 / 7-10期

关键词：

Microwave; Copper oxide; Acetylene black; Heterogeneous; Catalyst; Click reaction; NANOSTRUCTURES; CHEMISTRY; CU2O;

D O I：

10.1007/s11244-010-9481-0

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

CuO hollow nanospheres on acetylene black (CuO/AB) have been used for the catalytic [3 + 2] cycloaddition of azides with terminal alkynes without solvent, and within 1 min under microwave irradiation. The CuO/AB was readily separated by centrifugation, and could be reused five times under the present reaction conditions without any loss of catalytic activity.

引用

页码：523 / 528

页数：6

共 50 条

[21] Surface modification of magnetic nanoparticle via Cu(I)-Catalyzed alkyne-azide [2+3] cycloaddition
Lin, Po-Chiao
Ueng, Shau-Hua
Yu, Sheng-Chieh
Jan, Mi-Dan
Adak, Avijit Kumar
Yu, Ching-Ching
Lin, Chun-Cheng
ORGANIC LETTERS, 2007, 9 (11) : 2131 - 2134
[22] Versatile modifications to peptidomimetic sidechains by azide-alkyne [3+2] cycloaddition reactions.
Jang, HJ
Fafarman, AT
Kirshenbaum, K
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U89 - U89
[23] CuO hollow nanostructures catalyze [3+2] cycloaddition of azides with terminal alkynes
Kim, Jee Young
Park, Ji Chan
Kang, Hyuntae
Song, Hyunjoon
Park, Kang Hyun
CHEMICAL COMMUNICATIONS, 2010, 46 (03) : 439 - 441
[24] Sc(OTf)3-catalyzed [3+2]-cycloaddition of aziridines with nitriles under solvent-free conditions
Wu, J
Sun, XY
Xia, HG
TETRAHEDRON LETTERS, 2006, 47 (10) : 1509 - 1512
[25] Solvent-Free and Catalyst-Free Synthesis of Cross-Linkable Polyfumaramides via Topochemical Azide-Alkyne Cycloaddition Polymerization
Pathan, Javed R.
Sureshan, Kana M.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (29): : 9871 - 9878
[26] Microwave-promoted, solvent-free, three-component coupling of aldehyde, alkyne, and amine catalyzed by AgNO3
He, Tingting
Zha, Zhenggen
Pan, Chongfeng
Wang, Zhiyong
SYNTHETIC COMMUNICATIONS, 2007, 37 (4-6) : 849 - 858
[27] Base and concentration effects on the product distribution in copper-promoted alkyne-azide cycloaddition: additive-free route to 5-iodo-triazoles
Smith, Nicholas W.
Polenz, Bradley P.
Johnson, Shawna B.
Dzyuba, Sergei V.
TETRAHEDRON LETTERS, 2010, 51 (03) : 550 - 553
[28] CuO nanostructures of variable shapes as an efficient catalyst for [3+2] cycloaddition of azides with terminal alkyne
Kaur, Anupamjeet
Mann, Sukhmani
Goyal, Bhupesh
Pal, Bhupender
Goyal, Deepti
RSC ADVANCES, 2016, 6 (104) : 102733 - 102743
[29] Intramolecular azide-alkyne [3+2] cycloaddition: versatile route to new heterocyclic structural scaffolds
Li, Rongti
Jansen, Daniel J.
Datta, Apurba
ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (09) : 1921 - 1930
[30] Copper free intramolecular β-lactam tethered azide-alkyne [3+2] cycloaddition: An efficient synthesis of enantiopure tricyclic β-lactam triazoles
Paniagua, Armando
Chandra, Sunena
Yadav, Ram N.
Bandyopadhyay, Debasish
Banik, Bimal K.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248

← 1 2 3 4 5 →