Solvent-Free Microwave Promoted [3+2] Cycloaddition of Alkyne-Azide in Uniform CuO Hollow Nanospheres

被引：21
|
作者：
Kang, Hyuntae [1 ,3 ]
Lee, Hyun Ju [1 ,3 ]
Park, Ji Chan [2 ]
Song, Hyunjoon [2 ]
Park, Kang Hyun [1 ,3 ]
机构：
[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[3] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea
来源：
TOPICS IN CATALYSIS | 2010年 / 53卷 / 7-10期
关键词：
Microwave; Copper oxide; Acetylene black; Heterogeneous; Catalyst; Click reaction; NANOSTRUCTURES; CHEMISTRY; CU2O;
D O I：
10.1007/s11244-010-9481-0
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
CuO hollow nanospheres on acetylene black (CuO/AB) have been used for the catalytic [3 + 2] cycloaddition of azides with terminal alkynes without solvent, and within 1 min under microwave irradiation. The CuO/AB was readily separated by centrifugation, and could be reused five times under the present reaction conditions without any loss of catalytic activity.
引用
收藏
页码：523 / 528
页数：6
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