Cathode performance: The influence of design, operations, and operating conditions

There have been tremendous advances in the materials, knowledge, design, and construction of cathodes; however, widely divergent cell operations and operating conditions present a challenge for selecting the right materials and lining design for good cell life. Cathode wear is frequently becoming the life-determining step, and, although there are questions still to be answered, it is probable that particulate detachment (physical wear) plays an important role in parallel with carbide dissolution. If wear cannot be controlled by smart design and operations, coating technology may offer benefits for extending the life of cathode linings by reducing or eliminating wear. Thus, it would also enable softer graphitic materials to be utilized more readily, and this advantage will become more important if the trend toward higher current density continues.