Bright white-light emission from a novel donor-acceptor organic molecule in the solid state via intermolecular charge transfer

被引:89
|
作者
Jin, Xu-Hui [1 ]
Chen, Cheng [1 ]
Ren, Cai-Xia [1 ]
Cai, Li-Xuan [1 ]
Zhang, Jie [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
EMITTING-DIODES; TRANSFER COMPLEXES; EXCIPLEX FORMATION; FLUORESCENCE; ELECTROLUMINESCENCE; COMPONENT;
D O I
10.1039/c4cc07063a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bright white-light emission was obtained from a novel pyridinium molecule by aggregation. Photophysical, single-crystal structural, and computational studies demonstrated that an additional low-energy emission was generated by the excitation of a new intermolecular charge-transfer (CT) band at the ground state that cooperates with the non-quenched high-energy monomer emission to produce white light.
引用
收藏
页码:15878 / 15881
页数:4
相关论文
共 50 条
  • [21] Pillararene-Induced Intramolecular Through-Space Charge Transfer and Single-Molecule White-Light Emission
    Li, Qi
    Wu, Yitao
    Cao, Jiajun
    Liu, Yang
    Wang, Zeju
    Zhu, Huangtianzhi
    Zhang, Haoke
    Huang, Feihe
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (19)
  • [22] Interrogating the Intramolecular Charge-Transfer State of a Julolidine-Anthracene Donor-Acceptor Molecule with Femtosecond Stimulated Raman Spectroscopy
    Lockard, Jenny V.
    Ricks, Annie Butler
    Co, Dick T.
    Wasielewski, Michael R.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (01): : 215 - 218
  • [23] Modulation of Fluorescence Resonance Energy Transfer Efficiency for White Light Emission from a Series of Stilbene-Perylene Based Donor-Acceptor Pair
    Maiti, Dibakar Kumar
    Bhattacharjee, Rameswar
    Datta, Ayan
    Banerjee, Arindam
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (44): : 23178 - 23189
  • [24] High-performance organic light-emitting diodes based on intramolecular charge-transfer emission from donor-acceptor molecules: Significance of electron-donor strength and molecular geometry
    Kulkarni, Abhishek P.
    Kong, Xiangxing
    Jenekhe, Samson A.
    ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (08) : 1057 - 1066
  • [25] Supramolecular assembly of dipeptide functionalized benzo[ghi] perylene monoimide directs white light emission via donor-acceptor interactions
    Manna, Manoj K.
    Rasale, Dnyaneshwar B.
    Das, Apurba K.
    RSC ADVANCES, 2015, 5 (109) : 90158 - 90167
  • [26] Aromatic Donor-Acceptor Charge-Transfer Interactions Reinforced Supramolecular Polymer Electrolyte for Solid-State Lithium Batteries
    Yan, Shuaishuai
    Wang, Zhan
    Liu, Fengxiang
    Zhou, Hangyu
    Liu, Kai
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (52)
  • [27] Efficient quantum theory for studying cold charge-transfer state dissociations in donor-acceptor heterojunction organic solar cells
    Zhang, Longlong
    Hao, Yuying
    Gao, Kun
    APPLIED PHYSICS LETTERS, 2020, 117 (12)
  • [28] Acceptor engineering of quinone-based cycloparaphenylenes via post-synthesis for achieving white-light emission in single-molecule
    Li, Xiaonan
    Liu, Lin
    Jia, Luyang
    Lian, Zhe
    He, Jing
    Guo, Shengzhu
    Wang, Ying
    Chen, Xuebo
    Jiang, Hua
    NATURE COMMUNICATIONS, 2025, 16 (01)
  • [29] Unique dual fluorescence emission in the solid state from a small molecule based on phenanthrocarbazole with an AIE luminogen as a single-molecule white-light emissive material
    Chatsirisupachai, Jirat
    Nalaoh, Phattananawee
    Kaiyasuan, Chokchai
    Chasing, Pongsakorn
    Sudyoadsuk, Taweesak
    Promarak, Vinich
    MATERIALS CHEMISTRY FRONTIERS, 2021, 5 (05) : 2361 - 2372
  • [30] Solid-state white-light emission from a pyrylium dye obtained in one synthetic step
    Resta, Ignacio Munoz
    Miravet, Juan F.
    Yamaji, Minoru
    Galindo, Francisco
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (41) : 14348 - 14352