Nickel-catalyzed isomerization of 2-methyl-3-butenenitrile

被引：63
|
作者：
Wilting, J
Müller, C
Hewat, AC
Ellis, DD
Tooke, DM
Spek, AL
Vogt, D
机构：
[1] Eindhoven Univ Technol, Lab Homogeneous Catalysis, NL-5600 MB Eindhoven, Netherlands
[2] Univ Utrecht, Dept Crystal & Struct Chem, Utrecht, Netherlands
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 01期
关键词：
D O I：
10.1021/om049206p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C-C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.
引用
收藏
页码：13 / 15
页数：3
相关论文
共 50 条
  • [1] Phosphonite Ligand Design for Nickel-Catalyzed 2-Methyl-3-butenenitrile Isomerization and Styrene Hydrocyanation
    Tauchert, Michael E.
    Kaiser, Thilo R.
    Goethlich, Alexander P. V.
    Rominger, Frank
    Warth, Daniel C. M.
    Hofmann, Peter
    [J]. CHEMCATCHEM, 2010, 2 (06) : 674 - 682
  • [2] Sterically demanding diphosphonite ligands -: Synthesis and application in nickel-catalyzed isomerization of 2-methyl-3-butenenitrile
    van der Vlugt, JI
    Hewat, AC
    Neto, S
    Sablong, R
    Mills, AM
    Lutz, M
    Spek, AL
    Müller, C
    Vogt, D
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (08) : 993 - 1003
  • [3] Theoretical and experimental study of the nickel-catalyzed isomerization of 2-Methyl-3-butenenitrile and the effect of a Lewis acid
    Liu, Kun
    Liu, Kai-Kai
    Cheng, Mu-Jeng
    Han, Ming-Han
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 822 : 29 - 38
  • [4] Nickel complexes involved in the isomerization of 2-methyl-3-butenenitrile
    Acosta-Ramirez, Alberto
    Flores-Gaspar, Areli
    Munoz-Hernandez, Miguel
    Arevalo, Alma
    Jones, William D.
    Garcia, Juventino J.
    [J]. ORGANOMETALLICS, 2007, 26 (07) : 1712 - 1720
  • [5] Elucidation of key factors in nickel-diphosphines catalyzed isomerization of 2-methyl-3-butenenitrile
    Liu, Kaikai
    Xin, Hongliang
    Han, Minghan
    [J]. JOURNAL OF CATALYSIS, 2019, 377 : 13 - 19
  • [6] Highly Efficient Nickel-Catalyzed 2-Methyl-3-butenenitrile Isomerization: Applications and Mechanistic Studies Employing the TTP Ligand Family
    Tauchert, Michael E.
    Warth, Daniel C. M.
    Braun, Sebastian M.
    Gruber, Irene
    Ziesak, Alexandra
    Rominger, Frank
    Hofmann, Peter
    [J]. ORGANOMETALLICS, 2011, 30 (10) : 2790 - 2809
  • [7] Nickel-catalyzed isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile: A kinetic study using in situ FTIR-ATR spectroscopy
    Bini, Laura
    Houben, Erwin J. E.
    Pidko, Evgeny A.
    Muller, Christian
    Vogt, Dieter
    [J]. CATALYSIS TODAY, 2010, 155 (3-4) : 271 - 278
  • [8] Isomerization of 2-methyl-3-butenenitrile with (bis-diphenylphosphinoferrocene)nickel compounds:: Catalytic and structural studies
    Acosta-Ramirez, Alberto
    Munoz-Hernandez, Miguel
    Jones, William D.
    Garcia, Juventino J.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (18) : 3895 - 3901
  • [9] Rational design of efficient steric catalyst for isomerization of 2-methyl-3-butenenitrile
    Liu, Kaikai
    Wang, Tiefeng
    Han, Minghan
    [J]. MOLECULAR CATALYSIS, 2020, 498
  • [10] The catalytic isomerization reactions of 2-methyl-3-butenenitrile into 3-pentenenitrile in ionic liquids
    Vallée, C
    Valério, C
    Chauvin, Y
    Niccolai, GP
    Basset, JM
    Santini, CC
    Galland, JC
    Didillon, B
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (01) : 71 - 81
12345