The catalytic isomerization reactions of 2-methyl-3-butenenitrile into 3-pentenenitrile in ionic liquids

被引：20
|
作者：
Vallée, C
Valério, C
Chauvin, Y
Niccolai, GP
Basset, JM
Santini, CC
Galland, JC
Didillon, B
机构：
[1] ESCPE Lyon, CNRS, UMR 9986, Lab Chim Organometall Surface, F-69626 Villeurbanne, France
[2] Rhodia Rech, Ctr Rech Lyon, Serv CAT, F-69192 St Fons, France
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 214卷 / 01期
关键词：
ionic liquid; ionic phosphine; biphasic catalysis; isomerization of 2-methyl-3-butenenitrile;
D O I：
10.1016/j.molcata.2003.11.031
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic isomerization reaction of 2-methyl-3-butenenitrile (2M3BN) into 3-pentenenitrile (3PN) has been performed in the presence of Ni(0) and phosphine complexes and in biphasic ionic liquid/organic solvent. Several neutral and ionic phosphines and ionic liquids have been tested, the best results for the reaction of isomerization in conversion, selectivity, and immobilization of the catalyst in the ionic liquid phase have been obtained with the (m-sulfophenyl)-diphenylphosphine sodium salt, [TPPMSNa] as ligand and 1-butyl-2,3-dimethylimidazolium-bis(trifluoromethylsulfonyl)imide [BMMI] [TFSI], as the ionic liquid. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：71 / 81
页数：11
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