Anionic synthesis of well-defined polymers with amine end groups

被引：0
|
作者：
Quirk, RP [1 ]
Lee, Y [1 ]
机构：
[1] Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA
来源：
MACROMOLECULAR SYMPOSIA | 2000年 / 157卷
关键词：
D O I：
10.1002/1521-3900(200007)157:1<161::AID-MASY161>3.0.CO;2-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The results for efficient tertiary and primary amine functionalization of polymeric organolithium compounds in hydrocarbon solution at room temperature are described for termination reactions with N-trimethylsilylbenzophenone imine, 3-dimethylaminopropyl chloride and 2,2,5,5-tetramethyl-1-(3-chloropropyl)-1-aza-2,5-disilacyclopentane. Functionalizations with the functionalized initiator, 2,2,5,5-tetramethyl-1-(3-lithiopropyl)-1-aza-2,5-disilacyclopentane are presented. Conditions for quantitative amine functionalization were observed for all of these reactions and reagents.
引用
收藏
页码：161 / 169
页数：9
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