Thermal and mechanical properties of Zr52.5Al10Ni10Cu15Be12.5 bulk metallic glass

被引:16
|
作者
Xiao, XS [1 ]
Fang, SS [1 ]
Xia, L [1 ]
Li, WH [1 ]
Hua, Q [1 ]
Dong, YD [1 ]
机构
[1] Shanghai Univ, Inst Mat, Shanghai 200072, Peoples R China
关键词
amorphous materials; transition metal alloys; mechanical properties; thermal analysis;
D O I
10.1016/S0925-8388(02)01073-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation, thermal stability and mechanical properties of Zr52.5Al10Ni10Cu15Be12.5 bulk amorphous alloy were investigated by means of X-ray diffraction, differential scanning calorimetry, differential thermal analysis and tensile strength measurements. Compared with the Zr65Al10Ni10Cu15 amorphous alloy, the substitution of 12.5 at.% Be for part of the Zr results from an off-eutectic alloy composition into a eutectic one, and enhances the reduced glass transition temperature T-rg (T-g/T-m) increase from 0.58 to 0.68, DeltaT(x) from 105 to 142 K, and causes a change in fracture strength from 1.33 to 1.75 GPa. These results can be explained on the basis of then-nodynarnics and topological packing changes by the addition of beryllium. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:324 / 328
页数:5
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