Dielectric properties of nanophase Ag2HgI4 and Ag2HgI4-Al2O3 nanocomposites

被引:13
|
作者
Potty, SSN
Khadar, MA [1 ]
机构
[1] Univ Kerala, Dept Phys, Trivandrum 695581, Kerala, India
[2] Ctr Mat Elect Technol, Thrissur, India
关键词
nanophase materials; nanocomposites; dielectric properties;
D O I
10.1007/BF02708385
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The dielectric properties of nanophase Ag2HgI4 and Ag2HgI4-Al2O3, nanocomposites at different frequencies have been studied over a temperature range covering the stability range of beta phase of Ag2HgI4 and beyond the beta to alpha phase transition temperature. epsilon', tan delta and sigma(a.c.) of nanophase Ag2HgI4 and Ag2HgI4-AI(2)O(3) nanocomposites were found to be larger than the reported values for polycrystalline pellets of Ag2HgI4, The dielectric properties of the nanocomposites were found to be a function of the wt,% of nano alumina, The observed changes are attributed to the grain boundary properties of nanophase materials and to the microsize space charge effects.
引用
收藏
页码:361 / 367
页数:7
相关论文
共 50 条
  • [41] SOLID PHASES IN THE SYSTEM AG2HGI4-CU2HGI4
    SUCHOW, L
    KECK, PH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (03) : 518 - 522
  • [42] INFLUENCE OF PREPARATION TECHNIQUE ON THE ELECTRICAL-CONDUCTIVITY OF AG2HGI4
    MELLANDER, BE
    FRIESEL, M
    PHYSICAL REVIEW B, 1987, 35 (15): : 7902 - 7905
  • [43] Comparative study of the kinetics and mechanism of solid-solid reaction of HgClI with Cu2HgI4 and Ag2HgI4
    Ahmad, A
    Beg, S
    Sarita
    Varshney, P
    ASIAN JOURNAL OF CHEMISTRY, 2006, 18 (02) : 1065 - 1072
  • [45] PRESSURE DEPENDENT RAMAN, AND CONDUCTIVITY STUDIES OF THE FAST ION CONDUCTORS CU2HGI4, AG2HGI4 AND TL2ZNI4
    MCOMBER, JI
    SHRIVER, DF
    RATNER, MA
    FERRARO, JR
    WALLING, PL
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1982, 43 (09) : 903 - 909
  • [46] High-pressure dissociation of silver mercury iodide, Ag2HgI4
    Parfitt, DC
    Hull, S
    Keen, DA
    Crichton, W
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (10) : 3715 - 3720
  • [47] PHASE DIAGRAM OF Ag2HgI4 FOR PRESSURES UP TO 1 GPa.
    Baranowski, B.
    Friesel, M.
    Lunden, A.
    Physica B: Physics of Condensed Matter & C: Atomic, Molecular and Plasma Physics, Optics, 1985, 139-140 : 263 - 265
  • [48] Towards a deeper understanding of physical and chemical properties of Ag2HgI4 and Cu2HgI4 defective crystals, from first principles calculations
    Dahmani, M.
    Ouahrani, Tarik
    Mebrouki, M.
    Reshak, A.H.
    Materials Science in Semiconductor Processing, 2014, 27 (01) : 433 - 445
  • [49] PHASE-DIAGRAM OF AG2HGI4 FOR PRESSURES UP TO 1 GPA
    BARANOWSKI, B
    FRIESEL, M
    LUNDEN, A
    PHYSICA B & C, 1986, 139 (1-3): : 263 - 265
  • [50] INHOMOGENEOUS COMPOSITION EFFECTS ON PHASE-TRANSITION IN AG2HGI4 CRYSTALS
    AKOPYAN, IK
    NOVIKOV, BV
    FIZIKA TVERDOGO TELA, 1984, 26 (07): : 1994 - 1999