Polymer-graphite composite: a versatile use and throw plastic chip electrode

被引:53
|
作者
Perween, Mosarrat [1 ,2 ,3 ]
Parmar, Dilip B. [1 ,2 ]
Bhadu, Gopala Ram [1 ,2 ]
Srivastava, Divesh N. [1 ,2 ,3 ]
机构
[1] Cent Salt & Marine Chem Res Inst, CSIR, Analyt Discipline, Bhavnagar 364002, Gujarat, India
[2] Cent Salt & Marine Chem Res Inst, CSIR, Centralized Instrument Facil, Bhavnagar 364002, Gujarat, India
[3] Cent Salt & Marine Chem Res Inst, CSIR, Acad Sci & Innovat Res, Bhavnagar 364002, Gujarat, India
关键词
SCREEN-PRINTED ELECTRODES; CARBON-PASTE; ELECTROCHEMICAL CHARACTERIZATION; ZINC ELECTRODEPOSITION; FABRICATION; NANOCOMPOSITES; POLYANILINE; SENSORS;
D O I
10.1039/c4an01405g
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We report an efficient plastic chip electrode (PCE) fabricated from a composite of graphite and poly(methyl methacrylate) by a simple solution casting method and promoted as an economically inexpensive, multipurpose disposable electrode for various applications. The TEM images of the filler (graphite) show that the material consists of single, as well as multi-layers. Thus, the self-standing and arid electrodes prepared were characterized for their material properties such as, microscopy (SEM and AFM), as well as thermal properties (TGA), mechanical (tensile strength) and electrical properties. A set of physical parameters were derived from these characterizations for sustainability of these electrodes in harsh off-laboratory conditions. The utility of these mechanically stable, bulk-conducting and high surface area electrodes were demonstrated in various well understood electrochemical protocols, such as cyclic voltammetry, stripping voltammetry, electropolymerization, electrowinning and amperometric sensing. The voltammetry data were compared with the data recorded on a conventional glassy carbon electrode.
引用
收藏
页码:5919 / 5926
页数:8
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