Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition

被引：2
|
作者：
Shapovalov, S. S. [1 ]
Tikhonova, O. G. [1 ]
Grigor'eva, M. O. [1 ]
Skabitskii, I., V [1 ]
Simonenko, N. P. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2019年 / 45卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
carbonyls; nitrosyls; IMe; carbene; imidazole-2-carboxylate; heterometallic complex; CARBENE COMPLEXES; NANOPARTICLES; MANGANESE;
D O I：
10.1134/S1070328419100063
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heterometallic nickel and iron chalcogenide complexes, (eta(5)-C5H5)Ni(MeIm)S(mu(2)-(SPr)-Pr-n)Mn(CO)(2)(eta(5)-C5H5) (I) and (eta(5)-C5H5)Fe(MeIm)(CO)(mu(2)-SPh)Mn(CO)(2)(eta(5)-C5H5) (II), and the cobalt nitrosyl complex (MeIm)Co(NO)(2)I (IIIa, IIIb) (CIF files CCDC nos. 1911962 (I), 1911963 (II), 1911964 (IIIa), and 1911965 (IIIb)) are synthesized and structurally characterized. According to the data of thermogravimetry and differential scanning calorimetry (TG-DSC), the organic moiety of the molecule of complex I is lost to form the NiMnS residue, whereas ferrocene is formed upon the thermal decomposition of complex II.
引用
收藏
页码：706 / 711
页数：6
相关论文
共 50 条
  • [21] Transition Metal Complexes of N-Heterocyclic Germylenes
    Ullah, Farman
    Kuehl, Olaf
    Baior, Gabor
    Veszpremi, Tamas
    Jones, Peter G.
    Heinicke, Joachim
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (02) : 221 - 229
  • [22] Synthesis, structures and catalysis of Pd(II)-N-heterocyclic carbene complexes of pyridine/pyrimidine wingtip substituted ligand
    Samanta, Tapastaru
    Seth, Saikat Kumar
    Chattopadhyay, Shyamal Kumar
    Mitra, Partha
    Kushwah, Vandana
    Dinda, Joydev
    INORGANICA CHIMICA ACTA, 2014, 411 : 165 - 171
  • [23] β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis
    Kuwata, Shigeki
    Ikariya, Takao
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (13) : 3542 - 3556
  • [24] Synthesis of N-heterocyclic carbene boranes via silver N-heterocyclic carbene complexes
    Ono, Shintaro
    Watanabe, Takashi
    Nakamura, Yosuke
    Sato, Hiroyasu
    Hashimoto, Toru
    Yamaguchi, Yoshitaka
    POLYHEDRON, 2017, 137 : 296 - 305
  • [25] Discrete metal complexes from N-heterocyclic ferrocenes: Structural diversity by ligand design
    Horikoshi, Ryo
    COORDINATION CHEMISTRY REVIEWS, 2013, 257 (3-4) : 621 - 637
  • [26] Preparation, characterization, crystal structures and catalytic oxidation activities of two transition metal complexes of an N-heterocyclic pincer ligand
    Xuan Wang
    Na Xing
    Zhi Dan Yan
    Zhi Nan Wang
    Ji Xiao Wang
    Feng Ying Bai
    Yong Heng Xing
    Transition Metal Chemistry, 2015, 40 : 217 - 225
  • [27] Preparation, characterization, crystal structures and catalytic oxidation activities of two transition metal complexes of an N-heterocyclic pincer ligand
    Wang, Xuan
    Xing, Na
    Yan, Zhi Dan
    Wang, Zhi Nan
    Wang, Ji Xiao
    Bai, Feng Ying
    Xing, Yong Heng
    TRANSITION METAL CHEMISTRY, 2015, 40 (02) : 217 - 225
  • [28] Synthesis of N-heterocyclic chalcogenone silver complexes
    Voges-Haupt, Flannery
    Allen, Alexander
    Rabinovich, Daniel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [29] Multicomponent synthesis of N-heterocyclic carbene complexes
    Bon, Robin S.
    de Kanter, Frans J. J.
    Lutz, Martin
    Spek, Anthony L.
    Jahnke, Mareike C.
    Hahn, F. Ekkehardt
    Groen, Marinus B.
    Orru, Romano V. A.
    ORGANOMETALLICS, 2007, 26 (15) : 3639 - 3650
  • [30] Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium
    Liu, Hsueh-Ju
    Ziegler, Micah S.
    Tilley, T. Don
    DALTON TRANSACTIONS, 2018, 47 (35) : 12138 - 12146
12345