Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition

被引：2
|
作者：
Shapovalov, S. S. [1 ]
Tikhonova, O. G. [1 ]
Grigor'eva, M. O. [1 ]
Skabitskii, I., V [1 ]
Simonenko, N. P. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2019年 / 45卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
carbonyls; nitrosyls; IMe; carbene; imidazole-2-carboxylate; heterometallic complex; CARBENE COMPLEXES; NANOPARTICLES; MANGANESE;
D O I：
10.1134/S1070328419100063
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heterometallic nickel and iron chalcogenide complexes, (eta(5)-C5H5)Ni(MeIm)S(mu(2)-(SPr)-Pr-n)Mn(CO)(2)(eta(5)-C5H5) (I) and (eta(5)-C5H5)Fe(MeIm)(CO)(mu(2)-SPh)Mn(CO)(2)(eta(5)-C5H5) (II), and the cobalt nitrosyl complex (MeIm)Co(NO)(2)I (IIIa, IIIb) (CIF files CCDC nos. 1911962 (I), 1911963 (II), 1911964 (IIIa), and 1911965 (IIIb)) are synthesized and structurally characterized. According to the data of thermogravimetry and differential scanning calorimetry (TG-DSC), the organic moiety of the molecule of complex I is lost to form the NiMnS residue, whereas ferrocene is formed upon the thermal decomposition of complex II.
引用
收藏
页码：706 / 711
页数：6
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