New water-soluble fluorescent sensors based on calix[4]arene biscrown-6 for selective detection of cesium

被引：16

作者：

Xuan Qui Pham ^{[1
]}

Jonusauskaite, Laura ^{[1
]}

Depauw, A. ^{[1
]}

Kumar, Naresh ^{[1
]}

Lefevre, J. P. ^{[1
,2
]}

Perrier, Aurelie ^{[3
,4
]}

Minh-Huong Ha-Thi ^{[1
,5
]}

Leray, Isabelle ^{[1
]}

机构：

[1] Univ Paris Saclay, CNRS, ENS Paris Saclay, PPSM, 61 Ave President Wilson, F-94235 Cachan, France

[2] CNAM, 292 Rue St Martin, F-75003 Paris, France

[3] Univ Paris Diderot, Sorbonne Paris Cite, F-75205 Paris 13, France

[4] PSL Res Univ, Chim Paris Tech, CNRS, IRCP, F-75005 Paris, France

[5] Univ Paris Saclay, Univ Paris Sud, CNRS, ISMO, F-91405 Orsay, France

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2018年 / 364卷

关键词：

Fluorescent sensors; DFT; Calixarene; Cesium; 1,3-ALTERNATE; RECOGNITION; PHOSPHONATE; ETHER); CS+;

D O I：

10.1016/j.jphotochem.2018.06.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new fluorescent chemosensors based on calix[4]arene bis(crown-6) bearing coumarin units have been synthesized for the detection of cesium ions in water. The photophysical and complexing properties of these sensors with cesium were investigated using absorption and fluorescence spectroscopies as well as DFT calculations. The coordination of Cs+ by the these ligands induces a better charge transfer between the donor and acceptor groups of the coumarin, resulting in a bathochromic shift in absorption spectra and an enhancement of emission spectra. Both the ligands display an excellent selectivity for Cs+ over other potentially interfering cations such as Na+, Li+, K+, Mg2+, Ca2+ and Sr2+ ions.

引用

页码：355 / 362

页数：8

共 50 条

[31] A new highly selective calix[4] arene-based fluorescent probe for Ca2+
Liu, HB
Xu, Y
Li, BL
Yin, G
Xu, Z
CHEMICAL PHYSICS LETTERS, 2001, 345 (5-6) : 395 - 399
[32] Novel Water-Soluble Calix[4,6]arene Appended Magnetic Nanoparticles for the Removal of the Carcinogenic Aromatic Amines
Tuba Aksoy
Serkan Erdemir
H. Bekir Yildiz
Mustafa Yilmaz
Water, Air, & Soil Pollution, 2012, 223 : 4129 - 4139
[33] Cesium-selective optode membrane based on the lipophilic calix[4]biscrown in the 1,3-alternate conformation
Zeng, HH
Dureault, B
TALANTA, 1998, 46 (06) : 1485 - 1491
[34] New water-soluble calix[4]arene-bis(benzocrown-6) for caesium-sodium separation by nanofiltration-complexation
Pellet-Rostaing, S
Chitry, F
Spitz, JA
Sorin, A
Favre-Réguillon, A
Lemaire, M
TETRAHEDRON, 2003, 59 (51) : 10313 - 10324
[35] Water-soluble neutral calix[4]arene-lanthanide complexes: Synthesis and luminescence properties
Steemers, FJ
Meuris, HG
Verboom, W
Reinhoudt, DN
vanderTol, EB
Verhoeven, JW
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (13): : 4229 - 4235
[36] New Calix[4]arene Dibenzocrown Ethers for Selective Sensing of Cesium Ion in an Aqueous Environment
Jong, Seung Kim
Ill Yong Yu
Jin Hyun Pang
Jong Kuk Kim
Microchemical Journal, 58 (02):
[37] Structure, molecular dynamics, and host-guest interactions of a water-soluble calix[4]arene
Antony, JH
Dölle, A
NMR IN SUPRAMOLECULAR CHEMISTRY, 1999, 526 : 311 - 314
[38] Interactions of a water-soluble calix[4]arene with spermine: solution and solid-state characterisation
D'Urso, Alessandro
Brancatelli, Giovanna
Hickey, Neal
Farnetti, Erica
De Zorzi, Rita
Bonaccorso, Carmela
Purrello, Roberto
Geremia, Silvano
SUPRAMOLECULAR CHEMISTRY, 2016, 28 (5-6) : 499 - 505
[39] Spectroscopic studies of Brilliant Cresyl Blue water-soluble sulfonated calix[4]arene complex
Zhang, YL
Pham, TH
Pena, MS
Agbaria, RA
Warner, IM
APPLIED SPECTROSCOPY, 1998, 52 (07) : 952 - 957
[40] Interaction of water-soluble calix[4]arene with L-tryptophan studied by fluorescence spectroscopy
Li, Wen Ye
Li, Hui
Zhang, Guo Mei
Bin Chao, Jian
Ling, Li Xia
Shuang, Shao Min
Dong, Chuan
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 197 (2-3) : 389 - 393

← 1 2 3 4 5 →