Polystyrene-supported palladium(II) N,N-dimethylethylenediamine complex: A recyclable catalyst for Suzuki-Miyaura cross-coupling reactions in water

被引：7

作者：

Balaswamy, Kodicherla ^{[1
]}

Pullaiah, Perumgani C. ^{[1
]}

Srinivas, Keesara ^{[1
]}

Rao, Mandapati Mohan ^{[1
]}

机构：

[1] CSIR, Indian Inst Chem Technol, I&PC Div, Hyderabad 500607, Andhra Pradesh, India

来源：

INORGANICA CHIMICA ACTA | 2014年 / 423卷

关键词：

Polymer anchored Pd(II) catalyst; Suzuki-Miyaura coupling; Arylboronic acid; Aryl bromide; Aqueous solution; HETEROGENEOUS CATALYST; PD(II) COMPLEX; BASE COMPLEX; SONOGASHIRA; EFFICIENT; RESIN; HECK; ST1571;

D O I：

10.1016/j.ica.2014.07.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polystyrene-supported Pd(II) N,N-dimethylethylenediamine complex was prepared and characterized by various techniques, including Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), atomic absorption spectroscopy (AAS), and thermal analysis (TG-DTA). This heterogeneous Pd(II) catalyst works efficiently for the Suzuki-Miyaura coupling of arylboronic acids with aryl bromides in aqueous medium. The effect of base, and additives for the C-C coupling reactions were reported. Further, the catalyst can be easily recovered quantitatively by simple filtration and reused up to five times without significant loss in its catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：95 / 100

页数：6

共 50 条

[1] Polystyrene-supported palladium(II) N,N-dimethylethylenediamine complex: A recyclable catalyst for Suzuki-Miyaura cross-coupling reactions in water
Kodicherla, Balaswamy
Perumgani C., Pullaiah
Keesara, Srinivas
Mandapati, Mohan Rao
Inorganica Chimica Acta, 2014, (PA) : 95 - 100
[2] Silica supported palladium-phosphine complex: recyclable catalyst for Suzuki-Miyaura cross-coupling reactions at ambient temperature
Chen, Wei
Li, Pinhua
Wang, Lei
TETRAHEDRON, 2011, 67 (02) : 318 - 325
[3] Non-cross-linked polystyrene-supported triphenylphosphine-microencapsulated palladium: An efficient and recyclable catalyst for Suzuki-Miyaura reactions
He, HS
Yan, JJ
Shen, RX
Zhuo, SJ
Toy, PH
SYNLETT, 2006, (04) : 563 - 566
[4] Palladium supported on triazolyl-functionalized polysiloxane as recyclable catalyst for Suzuki-Miyaura cross-coupling
Mieczynska, E.
Borkowski, T.
Cypryk, M.
Pospiech, P.
Trzeciak, A. M.
APPLIED CATALYSIS A-GENERAL, 2014, 470 : 24 - 30
[5] Imidazolium supported palladium-chloroglycine complex: recyclable catalyst for Suzuki-Miyaura coupling reactions
Karthikeyan, Parasuraman
Vanitha, Arumugam
Radhika, Pachaiappan
Suresh, Kannan
Sugumaran, Arunachalam
TETRAHEDRON LETTERS, 2013, 54 (52) : 7193 - 7197
[6] Magnetic Nanoparticle-Supported N-Heterocyclic Carbene-Palladium(II): A Convenient, Efficient and Recyclable Catalyst for Suzuki-Miyaura Cross-Coupling Reactions
Vishal, K.
Fahlman, Bradley D.
Sasidhar, B. S.
Patil, Shivaputra A.
Patil, Siddappa A.
CATALYSIS LETTERS, 2017, 147 (04) : 900 - 918
[7] Suzuki-miyaura cross-coupling reactions catalyzed by N-heterocyclic carbene palladium complex
Shi, Ji-Cheng
Cao, Xin-Hua
Zheng, Ying
Jia, Li
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2007, 27 (05) : 666 - 669
[8] Palladium Supported on Silk Fibroin for Suzuki-Miyaura Cross-Coupling Reactions
Rizzo, Giorgio
Albano, Gianluigi
Lo Presti, Marco
Milella, Antonella
Omenetto, Fiorenzo G.
Farinola, Gianluca M.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 2020 (45) : 6992 - 6996
[9] Palladium on activated carbon -: A recyclable catalyst for Suzuki-Miyaura cross-coupling of aryl chlorides in water
Lysén, M
Köhler, K
SYNTHESIS-STUTTGART, 2006, (04): : 692 - 698
[10] Homogeneous and Recyclable Palladium Catalysts: Application in Suzuki-Miyaura Cross-Coupling Reactions
King, Andrew K.
Brar, Aneelman
Li, Guigen
Findlater, Michael
ORGANOMETALLICS, 2023, 42 (17) : 2353 - 2358

← 1 2 3 4 5 →